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Merck
CN

159239

Sigma-Aldrich

2-溴苯甲醚

97%

别名:

1-溴-2-甲氧基苯

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About This Item

线性分子式:
BrC6H4OCH3
CAS号:
分子量:
187.03
Beilstein:
1859996
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

liquid

折射率

n20/D 1.573 (lit.)

bp

223 °C (lit.)

mp

2 °C (lit.)

密度

1.502 g/mL at 25 °C (lit.)

SMILES字符串

COc1ccccc1Br

InChI

1S/C7H7BrO/c1-9-7-5-3-2-4-6(7)8/h2-5H,1H3

InChI key

HTDQSWDEWGSAMN-UHFFFAOYSA-N

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一般描述

通过Taylor-Aris色谱技术,已对在超临界二氧化碳中无限稀释的2-溴茴香醚的扩散系数进行了评估。

应用

2-溴苯甲醚可用于合成不对称取代的联苯化合物。 它还可用于制备exo-[n.m.n.m]metacyclophanes家族(n,m>或= 3)。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2

WGK

WGK 1

闪点(°F)

208.4 °F

闪点(°C)

98 °C

个人防护装备

Eyeshields, Gloves

法规信息

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Diffusion coefficients of 2-fluoroanisole, 2-bromoanisole, allylbenzene and 1, 3-divinylbenzene at infinite dilution in supercritical carbon dioxide
Suarez-Iglesias O, et al.
Fluid Phase Equilibria, 260(2), 279-286 (2007)
Burns et al.
The Journal of organic chemistry, 65(17), 5185-5196 (2000-09-19)
A general strategy for the preparation of the family of exo-[n.m.n.m]metacyclophanes (n,m > or = 3) in 6-steps (starting from 2-bromoanisole) that utilizes a [2 + 2] approach to furnish the exo-metacyclophane ring in good to moderate yield is described.
Zhishan Xu et al.
Cancer letters, 447, 75-85 (2019-01-24)
Herein we present half-sandwich IrIII complexes [(η5-Cpxbiph)Ir(OˆC)Cl] containing OˆC(NHC)-chelating ligand as anticancer and antimetastasis agents. All the complexes displayed high potency in vitro against a wide range of cancer cells. In addition, Ir2 significantly curb tumor growth in a colon
Marta Elsheimer-Matulova et al.
Veterinary research, 51(1), 67-67 (2020-05-15)
In attempt to identify genes that are induced in chickens by Salmonella Enteritidis we identified a new highly inducible gene, interleukin 4 induced 1 gene (IL4I1). IL4I1 reached its peak expression (458× induction) in the cecum of newly hatched chickens 4 days
Patrick T Weiser et al.
Bioorganic & medicinal chemistry, 22(2), 917-926 (2013-12-24)
A series of unsymmetrically substituted biphenyl compounds was designed as alpha helical proteomimetics with the aim of inhibiting the binding of coactivator proteins to the nuclear hormone receptor coactivator binding domain. These compounds were synthesized in good overall yields in

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