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质量水平
检测方案
99%
形式
liquid
折射率
n20/D 1.535 (lit.)
bp
198-202 °C (lit.)
mp
−18 °C (lit.)
密度
1.164 g/mL at 25 °C (lit.)
SMILES字符串
COc1ccc(Cl)cc1
InChI
1S/C7H7ClO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
InChI key
YRGAYAGBVIXNAQ-UHFFFAOYSA-N
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一般描述
4-氯茴香醚是一种富含电子的氯芳烃。它在原位生成的钯胶体催化下进行了乌尔曼型均偶联。正己烷、四氯化碳或二氯甲烷中4-氯茴香醚与铜（II）-蒙脱石的反应已被研究。4-氯茴香醚的亲核取代反应、光化学反应和光水解反应已通过时间分辨光谱法进行了研究。
WGK
WGK 3
闪点(°F)
165.2 °F
闪点(°C)
74 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Single electron transfer mechanism of oxidative dechlorination of 4-chloroanisole on copper (II)-smectite.
Govindaraj N, et al.
Environmental Science & Technology, 21(11), 1119-1123 (1987)
Antonio Monopoli et al.
The Journal of organic chemistry, 75(11), 3908-3911 (2010-05-14)
An efficient and highly sustainable Ullmann-type homocoupling of bromo- and chloroarenes, including the more challenging electron-rich chloroarenes (e.g., 4-chloroanisole), catalyzed by in situ generated Pd colloids, is carried out in aqueous medium under relatively mild conditions (temperatures ranging from 40
Laser spectroscopic study of the nucleophilic photosubstitution of 4-chloroanisole and 4-fluoroanisole in aqueous solutions.
Lemmetyinen H, et al.
Journal of Photochemistry, 30(3), 315-338 (1985)
Qingqing Mei et al.
Science advances, 4(5), eaaq0266-eaaq0266 (2018-05-26)
Ether bond activation is very interesting because the synthesis of many valuable compounds involves conversion of ethers. Moreover, C-O bond cleavage is also very important for the transformation of biomass, especially lignin, which abundantly contains ether bonds. Developing efficient methods
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