159042
Luperox®P,叔-过氧苯甲酸丁酯
98%
别名:
过氧化苯甲酸叔丁酯, 过氧化叔丁基苯甲酸酯
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线性分子式:
C6H5COOOC(CH3)3
化学文摘社编号:
分子量:
194.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-382-2
Beilstein/REAXYS Number:
1342734
MDL number:
Assay:
98%
Form:
liquid
InChI key
GJBRNHKUVLOCEB-UHFFFAOYSA-N
InChI
1S/C11H14O3/c1-11(2,3)14-13-10(12)9-7-5-4-6-8-9/h4-8H,1-3H3
SMILES string
CC(C)(C)OOC(=O)c1ccccc1
vapor density
6.7 (vs air)
vapor pressure
3.36 mmHg ( 50 °C)
assay
98%
form
liquid
Quality Level
bp
75-76 °C/0.2 mmHg (lit.)
solubility
water: soluble 1.18 g/L
density
1.021 g/mL at 25 °C (lit.)
functional group
peroxide, phenyl
General description
报道了过氧化苯甲酸特丁酯（TBPB）-介导的2-异氰基二芳基插入1,4-二氧六环。
Application
氧化苯甲酸叔丁酯用作聚合和交联催化剂。它还在以下期间用作引发剂：
- 2,2,6,6-四甲基-1-哌啶氧基（TEMPO）-4-氧乙酰胺基-（3-丙基三乙氧基硅烷）接枝到聚（乙烯共聚辛烯）上
- 通过起始化学气相沉积制备共形聚（甲基丙烯酸环己酯）薄膜
Legal Information
Arkema Inc. 产品
Luperox is a registered trademark of Arkema Inc.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 3 - Org. Perox. C - Skin Irrit. 2 - Skin Sens. 1
存储类别
4.1A - Other explosive hazardous materials
wgk
WGK 2
flash_point_f
200.1 °F - closed cup
flash_point_c
93.4 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Jingjing Xu et al.
ACS applied materials & interfaces, 3(7), 2410-2416 (2011-06-08)
Conformal poly(cyclohexyl methacrylate) (pCHMA) thin films were synthesized via initiated chemical vapor deposition (iCVD), with tert-butyl peroxybenzoate (TBPOB) as the initiator, representing the first time that TBPOB has been used as an initiator for iCVD synthesis. Using TBPOB instead of
Jia-Jia Cao et al.
Chemical communications (Cambridge, England), 50(49), 6439-6442 (2014-04-05)
An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C-C bonds were formed in this reaction via a sequential C(sp(3))-H/C(sp(2))-H bond functionalization under metal-free conditions.
Chengguo Liu et al.
Polymers, 11(5) (2019-05-10)
New tung oil (TO)-based, unsaturated, co-ester (Co-UE) macromonomers bearing steric hindrance were synthesized by modifying a TO-based maleate (TOPERMA) monomer with an anhydride structure with hydroxyethyl methacrylate (HEMA) and methallyl alcohol (MAA), respectively. The obtained Co-UE monomers (TOPERMA-HEMA and TOPERMA-MAA)
Structural comparison of products from peroxide-initiated grafting of vinylsilane and silane-functionalized nitroxyl to hydrocarbon and polyolefin substrates.
Weaver JD, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 46(13), 4542-4555 (2008)
Margaret Hanausek et al.
Carcinogenesis, 25(3), 431-437 (2003-11-25)
Screening of newly synthesized organic peroxides for tumor initiating/promoting activity would be greatly facilitated if predictive methodologies could be developed using topical exposures shorter than those required for definitive tumor assessment in mouse skin models. Nine organic peroxides [benzoyl peroxide
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