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蒸汽密度
6.7 (vs air)
质量水平
蒸汽压
3.36 mmHg ( 50 °C)
方案
98%
表单
liquid
折射率
n20/D 1.499 (lit.)
沸点
75-76 °C/0.2 mmHg (lit.)
溶解性
water: soluble 1.18 g/L
密度
1.021 g/mL at 25 °C (lit.)
官能团
peroxide
phenyl
SMILES字符串
CC(C)(C)OOC(=O)c1ccccc1
InChI
1S/C11H14O3/c1-11(2,3)14-13-10(12)9-7-5-4-6-8-9/h4-8H,1-3H3
InChI key
GJBRNHKUVLOCEB-UHFFFAOYSA-N
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一般描述
报道了过氧化苯甲酸特丁酯（TBPB）-介导的2-异氰基二芳基插入1,4-二氧六环。
应用
氧化苯甲酸叔丁酯用作聚合和交联催化剂。它还在以下期间用作引发剂：
- 2,2,6,6-四甲基-1-哌啶氧基（TEMPO）-4-氧乙酰胺基-（3-丙基三乙氧基硅烷）接枝到聚（乙烯共聚辛烯）上
- 通过起始化学气相沉积制备共形聚（甲基丙烯酸环己酯）薄膜
法律信息
Arkema Inc. 产品
Luperox is a registered trademark of Arkema Inc.
警示用语：
Danger
危险分类
Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 3 - Org. Perox. C - Skin Irrit. 2 - Skin Sens. 1
储存分类代码
4.1A - Other explosive hazardous materials
WGK
WGK 2
闪点(°F)
200.1 °F - closed cup
闪点(°C)
93.4 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Structural comparison of products from peroxide-initiated grafting of vinylsilane and silane-functionalized nitroxyl to hydrocarbon and polyolefin substrates.
Weaver JD, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 46(13), 4542-4555 (2008)
Jia-Jia Cao et al.
Chemical communications (Cambridge, England), 50(49), 6439-6442 (2014-04-05)
An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C-C bonds were formed in this reaction via a sequential C(sp(3))-H/C(sp(2))-H bond functionalization under metal-free conditions.
Chengguo Liu et al.
Polymers, 11(5) (2019-05-10)
New tung oil (TO)-based, unsaturated, co-ester (Co-UE) macromonomers bearing steric hindrance were synthesized by modifying a TO-based maleate (TOPERMA) monomer with an anhydride structure with hydroxyethyl methacrylate (HEMA) and methallyl alcohol (MAA), respectively. The obtained Co-UE monomers (TOPERMA-HEMA and TOPERMA-MAA)
Jingjing Xu et al.
ACS applied materials & interfaces, 3(7), 2410-2416 (2011-06-08)
Conformal poly(cyclohexyl methacrylate) (pCHMA) thin films were synthesized via initiated chemical vapor deposition (iCVD), with tert-butyl peroxybenzoate (TBPOB) as the initiator, representing the first time that TBPOB has been used as an initiator for iCVD synthesis. Using TBPOB instead of
Margaret Hanausek et al.
Carcinogenesis, 25(3), 431-437 (2003-11-25)
Screening of newly synthesized organic peroxides for tumor initiating/promoting activity would be greatly facilitated if predictive methodologies could be developed using topical exposures shorter than those required for definitive tumor assessment in mouse skin models. Nine organic peroxides [benzoyl peroxide
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