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质量水平
方案
99%
表单
solid
反应适用性
reaction type: C-C Bond Formation
mp
203-205 °C (lit.)
官能团
ketone
phosphine
SMILES字符串
CC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C21H19OP/c1-18(22)17-23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3
InChI key
KAANTNXREIRLCT-UHFFFAOYSA-N
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应用
作为以下反应的反应物：
- 对映体选择性合成茚满衍生物的级联反应
- 对映选择性共轭加成合成α-支链吲哚
- 合成具有抗锥虫活性的1,2-二恶烷
- 不对称烯丙基硼化，用于(+)-awajanomycin的对映选择性合成
- Domino Suzuki / Heck偶联反应，用于制备芴基
- 通过烯丙基胺化合成两栖吡咯并立生物碱
- 合成含硅无环二烯酮麝香香精
最近用于合成官能化吡咯烷和环丁酮的Wittig试剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Martin A Lovchik et al.
The Journal of organic chemistry, 72(7), 2427-2433 (2007-03-06)
Mechanistic studies on the intramolecular nucleophilic substitution with allylic rearrangement (SNi' reaction) and a new stereoselective access to substituted cyclobutanones are reported. 4,4-Dialkyl-5-oxohex-2E-en-1-yl methanesulfonates 4 were converted to 2,2-dialkyl-3-vinylcyclobutanones 6 by SNi' ring closure. The stereochemical analysis of the reaction
Synthesis, 1359-1359 (2007)
Liang-Chieh Chen et al.
Frontiers in pharmacology, 9, 708-708 (2018-07-19)
Alzheimer's disease (AD) is a progressive neurodegenerative disorder with multiple etiologies. Beta-amyloid (Aβ) self-aggregation and overexpression of class IIa histone deacetylases (HDACs) are strongly implicated with AD pathogenesis. In this study, a series of novel diarylheptanoid derivatives were designed, synthesized
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