一般描述
二苯并-18-冠-6-醚是一种大环配体,用于溶液相中碱金属阳离子的选择性结合和提取。
应用
相转移催化剂在单氮卟啉合成中的应用。用于离子跨膜转移 和作为合成子制备液晶聚酯的试剂。
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Binding selectivity of dibenzo-18-crown-6 for alkali metal cations in aqueous solution: A density functional theory study using a continuum solvation model
Chemistry Central Journal, 6, 1-8 (2012)
Tetrahedron Letters, 36, 1567-1567 (1995)
Solvent influence upon complex formation between dibenzo-18-crown-6 with the Y3+ metal cation in pure and binary mixed organic solvents
Journal of Chemical and Engineering Data, 56, 2836-2840 (2011)
Acta Polym., 45, 308-308 (1994)
Dalton transactions (Cambridge, England : 2003), 40(7), 1491-1496 (2011-01-19)
A supramolecular cation of (m-FAni(+))(DB[18]crown-6), where m-FAni(+) and DB[18]crown-6 denote m-fluoroanilinium(+) and dibenzo[18]crown-6, respectively, which is the polar unit rotating in the ferroelectric crystal of (m-FAni(+))(DB[18]crown-6)[Ni(dmit)(2)](-), was introduced into a ferromagnetic [MnCr(oxalate)(3)](-) salt as the counter cation. The crystal structure
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