质量水平
检测方案
97%
形式
solid
mp
52-54 °C (lit.)
SMILES字符串
C1CSCSC1
InChI
1S/C4H8S2/c1-2-5-4-6-3-1/h1-4H2
InChI key
WQADWIOXOXRPLN-UHFFFAOYSA-N
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一般描述
1,3-二噻烷，一种受保护的甲醛阴离子当量，用作有用的标记合成子。
应用
以 1，3-二噻烷为脱氧剂，将亚砜脱氧成相应的硫化物。
WGK
WGK 3
闪点(°F)
194.0 °F
闪点(°C)
90 °C
个人防护装备
Eyeshields, Gloves, type N95 (US)
Al-Monsur Jiaul Haque et al.
Chemical communications (Cambridge, England), (32)(32), 4865-4867 (2009-08-05)
We report the use of 1,3-dithiane combined with aryldiazonium cation for the immobilization of biomolecules based on electrochemical addressing.
Yuncong Chen et al.
Chemical communications (Cambridge, England), 48(42), 5094-5096 (2012-04-20)
A novel sensitive and specific Hg(2+) chemodosimeter, derived from 1',3'-dithiane-substituted 2,1,3-benzoxadiazole, displays "turn-on" fluorescent and colorimetric responses via an Hg(2+)-triggered aldehyde recovery reaction. Its potential to monitor Hg(2+) in living organisms has been demonstrated using zebrafish larvae.
A I Noskov et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 77(1), 6-10 (2010-07-17)
The IR spectra of 1,3-dithiane-1-oxide (I) and 1,3-dithia-1-oxocyclohept-5-ene (II) were recorded in solution, solid and liquid phase over 4000-400 cm(-1) spectral range. It was found that both (I) and (II) in liquid phase and solutions exist in two conformations: (I)
Rodolfo A Martinez et al.
Journal of labelled compounds & radiopharmaceuticals, 57(5), 338-341 (2014-05-28)
The 1,3-dithiane is a protected formaldehyde anion equivalent that could serve as a useful labeled synthon. We report a facile synthesis of 1,3-[2-(13)C]- and 1,3-[2-(13)C, 2-(2)H2]dithiane in two steps from [(13)C]- or [(13) C, (2)H3 ]methyl phenyl sulfoxide. We have
Valerie J Peterson et al.
The Biochemical journal, 362(Pt 1), 173-181 (2002-02-07)
Apo and holo forms of retinoic acid receptors, and other nuclear receptors, display differential sensitivity to proteolytic digestion that likely reflects the distinct conformational states of the free and liganded forms of the receptor. We have developed a method for
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