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安全信息

157759

Sigma-Aldrich

一氯化硫

98%

别名:

氯化硫

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About This Item

线性分子式:
S2Cl2
CAS号:
10025-67-9
分子量:
135.04
EC 号:
233-036-2
MDL编号:
MFCD00011446
UNSPSC代码:
12352302
PubChem化学物质编号:
24849698
NACRES:
NA.23
方案:
98%
表单:
liquid

蒸汽密度

4.7 (vs air)

质量水平

200

蒸汽压

6.8 mmHg ( 20 °C)

方案

98%

表单

liquid

自燃温度

451 °F

折射率

n20/D 1.658 (lit.)

沸点

138 °C (lit.)

mp

−80 °C (lit.)

密度

1.688 g/mL at 25 °C (lit.)

SMILES字符串

ClSSCl

InChI

1S/Cl2S2/c1-3-4-2

InChI key

PXJJSXABGXMUSU-UHFFFAOYSA-N

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一般描述

Sulfur monochloride is a yellowish-red liquid widely used as a reagent and intermediate in organic synthesis. It is also employed in manufacturing pesticides, pharmaceuticals, and dyes.

应用

Sulfur monochloride can be used:
  • To synthesize functionalized aryl and heteroaryl disulfides from functionalized zinc organometallics.
  • As a reagent to prepare heterocycles with various numbers of sulfur atoms.
  • As a cross-linking agent to prepare rubber aerogels with enhanced thermal stability.
  • Toprepare macroporous cryogels of polyisobutylene and silica nanoparticles.

警示用语：

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Skin Corr. 1A

补充剂危害

EUH014,EUH029

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB0801
STBL1448
STBK7970
STBJ9747
STBJ3311

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A direct preparation of functionalized aryl and heteroaryl disulfides from functionalized zinc organometallics by using sulfur monochloride (S2Cl2
Tobias J Korn and Paul Knochel
Synlett, 2005, 1185-1187 (2005)
Andrea Steinhaus et al.
Polymers, 11(7) (2019-07-03)
Lamella-forming ABC triblock terpolymers are convenient building blocks for the synthesis of soft Janus nanoparticles (JNPs) by crosslinking the B domain that is "sandwiched" between A and C lamellae. Despite thorough synthetic variation of the B fraction to control the
Solution cross-linked natural rubber(NR)/clay aerogel composite
Tassawuth Pojanavaraphan, et al
Macromolecules, 44, 923-931 (2011)
Hierarchically Macroporous Cryogels of Polyisobutylene and Silica Nanoparticles
Deniz C. Tuncaboylu and Oguz Okay
Langmuir, 26, 7574-7581 (2010)
Sulfur monochloride in organic synthesis
Lidia Sergeevna Konstantinova and Oleg Alexeevich Rakitin
Russ. Chem. Rev., 83, 225-225 (2014)
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