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157457

Sigma-Aldrich

3,5-二叔丁基邻苯醌

98%

别名:

3,5-二叔丁基-1,2-苯醌, 3,5-二叔丁基-o-苯醌, 3,5-二叔丁基环己基-3,5-二烯-1,2-二酮, 3,5-二叔丁基苯醌, 3,5-双(1,1-二甲基乙基)-3,5-环己二烯-1,2-二酮, 4,6-二叔丁基-1,2-苯醌, 4,6-二叔丁基-o-苯醌

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About This Item

线性分子式:
[(CH3)3C]2C6H2(=O)2
CAS号:
3383-21-9
分子量:
220.31
Beilstein:
2047944
EC 号:
222-189-0
MDL编号:
MFCD00001647
UNSPSC代码:
12352100
PubChem化学物质编号:
24849680
NACRES:
NA.22

质量水平

100

方案

98%

表单

solid

mp

112-114 °C (lit.)

SMILES字符串

CC(C)(C)C1=CC(=O)C(=O)C(=C1)C(C)(C)C

InChI

1S/C14H20O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8H,1-6H3

InChI key

NOUZOVBGCDDMSX-UHFFFAOYSA-N

基因信息

human ... ACHE(43) , BCHE(590) , CES1(1066)

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相关类别

一般描述

次膦基桥联络合物[[Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) 与3,5-二-叔-丁基-o-苯醌的反应已有报道。

应用

3,5-二-叔-丁基-o-苯醌可用于制备苯并恶唑衍生物配体。其可与无环二烯发生杂原子Diels Alder反应，制备1,4-苯二恶英。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000246708
0000243793
0000234429
0000243793
0000246708

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Akira Kotani et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(11), 1473-1476 (2003-12-03)
A disposable voltammetric cell using three pencil leads as working, reference, and counter electrodes was developed for determining the titratable acidity, i.e. the acid content in vinegar. The materials of the pencil leads were graphite-reinforcement carbons (GRCs). A voltammetric determination
Olga Iasco et al.
Inorganic chemistry, 51(4), 2588-2596 (2012-01-12)
Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or 1,3-diamino-2-hydroxypropane in methanol. Condensation of DTBBQ with ethanolamine gives the expected 5,7-di-tert-butyl-2-methylenhydroxylbenzoxazole (HL1) while with 1,3-diamino-2-hydroxypropane it gives (2-hydroxyethyl-2-{2,4-bis(1,1-dimethylethyl)-1-phenol-6 amino}-2{5,7-di-tert-butyl-benzoxazole}) (H(2)L2) with only one benzoxazole
Determination of natural thiols by liquid chromatography after derivatization with 3,5-di-tert.-butyl-1,2-benzoquinone.
Y Imai et al.
Journal of chromatography, 420(2), 404-410 (1987-09-25)
Chinmoy Das et al.
Dalton transactions (Cambridge, England : 2003), 46(5), 1439-1448 (2017-01-11)
The reaction of anhydrous MCl
Victor A Timoshchuk et al.
Nucleosides, nucleotides & nucleic acids, 28(5), 464-472 (2010-02-26)
A new method for the synthesis of fluorescent nucleosides has been developed. It has been shown that a reaction of benzoquinone with aminopropenyl group at C-5-position of 2'-deoxyuridine or 2'-deoxycytidine and aminopropynyl group at the C-7-position of 8-aza-7-deazaadenosine under extremely
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