157422
异戊酰氯
98%
别名:
3-甲基丁酰氯
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关于此项目
线性分子式:
(CH3)2CHCH2COCl
化学文摘社编号:
分子量:
120.58
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-552-2
Beilstein/REAXYS Number:
741910
MDL number:
Assay:
98%
refractive index
n20/D 1.416 (lit.)
bp
115-117 °C (lit.)
density
0.989 g/mL at 25 °C (lit.)
functional group
acyl chloride
InChI
1S/C5H9ClO/c1-4(2)3-5(6)7/h4H,3H2,1-2H3
InChI key
ISULZYQDGYXDFW-UHFFFAOYSA-N
SMILES string
CC(C)CC(Cl)=O
assay
98%
Quality Level
Application
异戊酰氯被用于合成：
- furanodictines A和B
- 四肽酰胺，S-苄基-L-半胱氨酰-L-脯氨酰-L-亮氨酰甘氨酰胺
- (+)-blastmycinone
- (R)- 和(S)-2甲基-4-辛醇，某些甘蔗象鼻虫的聚集信息素
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
87.8 °F - closed cup
flash_point_c
31 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
The Synthesis of the Tetrapeptide Amide S-Benzyl-L-cysteinyl-L-prolyl-L-leucylglycinamide
Ressler Cand Vincent du Vigneaud.
Journal of the American Chemical Society, 76(12), 3107-3109 (1954)
Makoto Ogata et al.
Carbohydrate research, 345(2), 230-234 (2009-12-08)
A novel synthesis of furanodictines A [2-acetamido-3,6-anhydro-2-deoxy-5-O-isovaleryl-D-glucofuranose (1)] and B [2-acetamido-3,6-anhydro-2-deoxy-5-O-isovaleryl-D-mannofuranose (2)] is described starting from 2-acetamido-2-deoxy-D-glucose (GlcNAc). The synthetic protocol is based on deriving the epimeric bicyclic 3,6-anhydro sugars [2-acetamido-3,6-anhydro-2-deoxy-D-glucofuranose (4) and 2-acetamido-3,6-anhydro-2-deoxy-D-mannofuranose (5)] from GlcNAc. Reaction with borate
Organoaluminium induced ring-opening of epoxypyranosides. V. Formal total synthesis of antimycin A3 and synthesis of (+)-blastmycinone.
Inghardt T and Frejd T.
Tetrahedron, 47(32), 6483-6492 (1991)
Jessica L Wojtaszek et al.
Cell, 178(1), 152-159 (2019-06-11)
Intrinsic and acquired drug resistance and induction of secondary malignancies limit successful chemotherapy. Because mutagenic translesion synthesis (TLS) contributes to chemoresistance as well as treatment-induced mutations, targeting TLS is an attractive avenue for improving chemotherapeutics. However, development of small molecules with
Seon-Mi Seo et al.
Pesticide biochemistry and physiology, 113, 55-61 (2014-07-24)
This study investigated the fumigant toxicity of 4 Asteraceae plant essential oils and their constituents against the Japanese termite Reticulitermes speratus Kolbe. Fumigant toxicity varied with plant essential oils or constituents, exposure time, and concentration. Among the tested essential oils
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