所有图片(2)
About This Item
线性分子式:
HCOC3H4CO2C2H5
CAS号:
分子量:
142.15
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
96%
表单
liquid
折射率
n20/D 1.452 (lit.)
沸点
60-65 °C/0.6 mmHg (lit.)
密度
1.074 g/mL at 25 °C (lit.)
官能团
aldehyde
ester
储存温度
2-8°C
SMILES字符串
CCOC(=O)C1CC1C=O
InChI
1S/C7H10O3/c1-2-10-7(9)6-3-5(6)4-8/h4-6H,2-3H2,1H3
InChI key
MDWXTLNIZCHBJE-UHFFFAOYSA-N
一般描述
Ethyl 2-formyl-1-cyclopropanecarboxylate was formed by acid catalyzed reaction between acrolein and ethyl diazoacetate.
应用
Ethyl 2-formyl-1-cyclopropanecarboxylate was used in the preparation of ethyl trans-2-(4-(methylphenyl)sulfonyl-4,5-dihydrooxazol-5-yl)cyclopropanecarboxylate.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
183.2 °F - closed cup
闪点(°C)
84 °C - closed cup
Acid catalyzed reactions of a, ?-unsaturated aldehydes and ethyl diazoacetate.
Branstetter B and Hossain MM.
Tetrahedron Letters, 47(2), 221-223 (2006)
I J De Esch et al.
Journal of medicinal chemistry, 42(7), 1115-1122 (1999-04-10)
Various approaches to the synthesis of all four stereoisomers of 2-(1H-imidazol-4-yl)cyclopropylamine (cyclopropylhistamine) are described. The rapid and convenient synthesis and resolution of trans-cyclopropylhistamine is reported. The absolute configuration of its enantiomers was determined by single-crystal X-ray crystallographic analysis. The distinct
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