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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.536 (lit.)
沸点
135 °C/20 mmHg (lit.)
密度
1.007 g/mL at 25 °C (lit.)
官能团
acyl chloride
SMILES字符串
CC(C)(C)c1ccc(cc1)C(Cl)=O
InChI
1S/C11H13ClO/c1-11(2,3)9-6-4-8(5-7-9)10(12)13/h4-7H,1-3H3
InChI key
WNLMYNASWOULQY-UHFFFAOYSA-N
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一般描述
AlCl3 promoted Friedel-Crafts acylation of 4-tert-butylbenzoyl chloride with mesitylene was investigated.
应用
4-tert-Butylbenzoyl chloride was used in the synthesis of 9,9′-spirobifluorene-bridged bipolar systems containing 1,3,4-oxadiazole-conjugated oligoaryl and triaryllamine moieties. It was also used in the preparation of 2-(4-tert-butylphenyl)-5-(4-methoxyphenyl)-1,3,4-oxadiazole.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
188.6 °F - closed cup
闪点(°C)
87 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
Yuh-Yih Chien et al.
Chemical communications (Cambridge, England), (23)(23), 2874-2875 (2002-12-14)
Some 9,9'-spirobifluorene-bridged bipolar systems 1-3 containing 1,3,4-oxadiazole-conjugated oligoaryl and triarylamine moieties have been synthesized, in which 1 exhibits remarkable solvent-polarity dependent fluorescence properties due to a highly efficient photoinduced electron transfer reaction.
Statistical copolymers with side-chain hole and electron transport groups for single-layer electroluminescent device applications.
Jiang X, et al.
Chemistry of Materials, 12(9), 2542-2549 (2000)
Zhiliang Huang et al.
Organic & biomolecular chemistry, 11(11), 1810-1814 (2013-02-08)
AlCl(3) promoted Friedel-Crafts acylation between 4-tert-butylbenzoyl chloride and mesitylene was investigated. The donor-acceptor complex was observed as the major species. Kinetic investigation demonstrated that the reaction was first-order on the donor-acceptor complex and zero-order on ArH, suggesting that the donor-acceptor
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