156876
N-羟乙基苯胺
98%
别名:
2-苯氨基乙醇, 2-苯胺乙醇, N-苯基乙醇胺
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线性分子式:
C6H5NHCH2CH2OH
化学文摘社编号:
分子量:
137.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
774672
Assay:
98%
Form:
liquid
refractive index
n20/D 1.578 (lit.)
bp
278-282 °C/760 mmHg (lit.)
density
1.094 g/mL at 25 °C (lit.)
InChI
1S/C8H11NO/c10-7-6-9-8-4-2-1-3-5-8/h1-5,9-10H,6-7H2
SMILES string
OCCNc1ccccc1
InChI key
MWGATWIBSKHFMR-UHFFFAOYSA-N
vapor density
>1 (vs air)
vapor pressure
<0.01 mmHg ( 20 °C)
assay
98%
form
liquid
Quality Level
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Application
N-（2-羟乙基）苯胺被用作人嗅觉UDP-葡糖醛酸糖基转移酶的底物。
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 - STOT SE 1
target_organs
Blood, Blood,hematopoietic system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Marco Santarem et al.
The Journal of organic chemistry, 73(16), 6466-6469 (2008-07-22)
An efficient formal total synthesis of (+)-gephyrotoxin is described. The key step of our strategy relies on the diastereoselective reduction of a chiral pyrrolidine beta-enamino ester obtained by condensation of ( S)-phenylglycinol on a protected 8-hydroxy-3,6-dioxooctanoate.
Mercedes Amat et al.
Chemical communications (Cambridge, England), (20)(20), 2935-2937 (2009-05-14)
The first total synthesis of (-)-16-episilicine has been completed from a phenylglycinol-derived bicyclic lactam, the key steps being stereoselective conjugate addition and alkylation reactions, and a ring-closing metathesis.
Katarina Babić et al.
Journal of chromatography. A, 1142(1), 84-92 (2006-10-19)
The performance of extractant impregnated resin (EIR) technology for chiral separation of amino-alcohols has been investigated. Phenylglycinol was selected as an archetype model enantiomer and azophenolic crown ether was used as a versatile enantioselective extractant. 1-Phenyloctane was selected as a
Mercedes Amat et al.
Organic & biomolecular chemistry, 9(7), 2175-2184 (2011-02-08)
The double cyclocondensation of symmetric pyridyl bis(oxoacids) 2b and 3b with (R)-phenylglycinol stereoselectively gave access to bis-phenylglycinol-derived oxazolopyrrolidine 9 and oxazolopiperidone 10, respectively. Application of the stereocontrolled cyclocondensation reaction to phenyl bis-γ-oxoacid 4b provided 11, which was converted to the
Alok K Awasthi et al.
The Journal of organic chemistry, 70(14), 5387-5397 (2005-07-02)
[reaction: see text] A practical, large-scale synthesis of a beta-amino ester 1 was developed. A chiral imine derived from (S)-phenylglycinol and 3-trimethylsilylpropanal was coupled with the Reformatsky reagent 3 with high diastereoselectivity (de > 98%) to give (SS)-4a as the
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