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同位素纯度
99.8 atom % D
质量水平
检测方案
99% (CP)
形式
liquid
包含
1 % (v/v) TMS
技术
NMR: suitable
杂质
≤0.0100% water
water
折射率
n20/D 1.444 (lit.)
bp
60.9 °C (lit.)
mp
−64 °C (lit.)
密度
1.500 g/mL at 25 °C (lit.)
质量偏移
M+1
SMILES字符串
[2H]C(Cl)(Cl)Cl
InChI
1S/CHCl3/c2-1(3)4/h1H/i1D
InChI key
HEDRZPFGACZZDS-MICDWDOJSA-N
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一般描述
氯仿-d(氘代氯仿,CDCl 3 )是氯仿的氘代衍生物。含有 1% (v/v) TMS(四甲基硅烷,作为稳定剂加入)。本文报道了氯仿-d 在不同有机溶剂中的碳氘伸缩峰的定量红外光谱研究。 用 Raman 差谱研究了氯仿-d 和液体氯仿混合物在 cCHCl3 和 CDCl3 的1 和 2 谱带中的频移。
应用
氯仿-d 已被用作氘代溶剂,用于含 α-苯乙基的 β-氨基丙酸相应手性衍生物的 NMR 谱研究,它们可作为 β-氨基酸不对称合成的有用起始原料。
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警示用语:
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3
靶器官
Liver,Kidney, Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
Preparation of chiral derivatives of ?-Ala containing the a-phenylethyl group: useful starting materials for the asymmetric synthesis of ?-amino acids
Nature Protocols, 2(11), 2759-2766 (2007)
Isotopic dilution studies of the chloroform-chloroform-d system by Raman difference spectroscopy.
J. Chem. Phys. , 73(10), 4971-4975 (1980)
Nature protocols, 2(11), 2759-2766 (2007-11-17)
The use of microwave (MW) irradiation for the condensation reaction between acetophenone and alpha-phenylethylamine to prepare (R,R)-bis[alpha-phenylethyl]amine results in significantly reduced reaction times relative to the use of conventional heating. In this protocol, a secondary amine, (R,R)-bis(alpha-phenylethyl)amine is treated with
Quantitative Study of the Bonding of Chloroform-d in Various Solvents by Infrared Spectrometry1.
Journal of the American Chemical Society, 77(5), 1365-1368 (1955)
Plant biotechnology journal, 13(6), 821-832 (2015-01-13)
Bacteria-derived enzymes that can modify specific lignin substructures are potential targets to engineer plants for better biomass processability. The Gram-negative bacterium Sphingobium sp. SYK-6 possesses a Cα-dehydrogenase (LigD) enzyme that has been shown to oxidize the α-hydroxy functionalities in β-O-4-linked
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