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经验公式(希尔记法):
C6H8ClN2O5P
化学文摘社编号:
分子量:
254.56
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3654596
产品名称
双(2-氧代-3-噁唑烷基)次磷酰氯, ≥97.0% (AT)
InChI
1S/C6H8ClN2O5P/c7-15(12,8-1-3-13-5(8)10)9-2-4-14-6(9)11/h1-4H2
SMILES string
ClP(=O)(N1CCOC1=O)N2CCOC2=O
InChI key
KLDLRDSRCMJKGM-UHFFFAOYSA-N
assay
≥97.0% (AT)
form
solid
mp
191 °C (dec.) (lit.)
Quality Level
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Other Notes
活化羧基,合成酰胺、酯、肽 的试剂
Application
Bis(2-oxo-3-oxazolidinyl)phosphinic chloride was used in the preparation of hexadepsipeptide.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Zhao Yanbin et al.
Biochemical and biophysical research communications, 516(1), 102-111 (2019-06-16)
Here, we firstly examined the proliferation and invasion capacities of different osteosarcoma (OS) cell lines, and analyzed the profiling of the differentially expressed circular RNAs(circRNAs). Then, we identified a novel circRNA(circ_101356/circ_0004846, we named circSAMD4 in the present study) and found
S. Danishefsky et al
Tetrahedron Letters, 25, 4203-4203 (1984)
J. Cabre et al.
Synthesis, 413-413 (1984)
Yanjie Xu et al.
Molecules (Basel, Switzerland), 10(1), 259-264 (2007-11-17)
Hexadepsipeptide 2, the precursor of Hirsutellide A (1), was synthesized in an overall yield of 45% from N-Boc-Me-Gly via three coupling reactions using dicyclohexylcarbodiimide (DCC), O-(7-azabenzotriazol-1-yl)-N,N,N',N'-tetramethyl- uronium hexafluorophosphate (HATU) and bis(2-oxo-3-oxazolidinyl)phosphinic chloride (BOP-Cl), respectively.
R.D. Tung et al.
Journal of the American Chemical Society, 107, 4342-4342 (1985)
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