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质量水平
方案
99%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.498 (lit.)
沸点
88-90 °C (lit.)
mp
−90 °C (lit.)
密度
1.703 g/mL at 25 °C (lit.)
官能团
alkyl halide
iodo
SMILES字符串
CC(C)I
InChI
1S/C3H7I/c1-3(2)4/h3H,1-2H3
InChI key
FMKOJHQHASLBPH-UHFFFAOYSA-N
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一般描述
2-碘丙烷是一种有机碘化合物。它通常用作均裂和异裂烷基化剂，用于制备 α-异丙氧基亚甲基保护基团。此外，它还作为硫代碳酸盐转化为烯烃的中间体。
应用
2-碘丙烷（异丙基碘）被用于制备丁酸和异丁酸。
2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物（吲哚、吡啶、嘌呤、四唑、吡唑和胺）转化为对应产物。
2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物（吲哚、吡啶、嘌呤、四唑、吡唑和胺）转化为对应产物。
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
107.6 °F - closed cup
闪点(°C)
42 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
2-Iodopropane
Wilson PD and Hilmey DG
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
John J Orlando et al.
The journal of physical chemistry. A, 109(30), 6659-6675 (2006-07-13)
The reaction of Cl atoms with iodoethane has been studied via a combination of laser flash photolysis/resonance fluorescence (LFP-RF), environmental chamber/Fourier transform (FT)IR, and quantum chemical techniques. Above 330 K, the flash photolysis data indicate that the reaction proceeds predominantly
W Kenealy et al.
Journal of bacteriology, 146(1), 133-140 (1981-04-01)
Iodopropane inhibited cell growth and methane production when Methanobacterium thermoautotrophicum, Methanobacterium formicicum, and Methanosarcina barkeri were cultured on H2-CO2. Iodopropane (40 microM) inhibited methanogenesis (30%) and growth (80%) when M. barkeri was cultured mixotrophically on H2-CO2-methanol. The addition of acetate
Development and validation of analytical procedure--control of residual 2-iodopropane in latanoprost.
Aleksandra Groman et al.
Acta poloniae pharmaceutica, 67(6), 673-676 (2011-01-15)
Timur Coskun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
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