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质量水平
方案
99%
表单
liquid
包含
copper as stabilizer
折射率
n20/D 1.498 (lit.)
沸点
88-90 °C (lit.)
mp
−90 °C (lit.)
密度
1.703 g/mL at 25 °C (lit.)
官能团
alkyl halide
iodo
SMILES字符串
CC(C)I
InChI
1S/C3H7I/c1-3(2)4/h3H,1-2H3
InChI key
FMKOJHQHASLBPH-UHFFFAOYSA-N
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一般描述
2-碘丙烷是一种有机碘化合物。它通常用作均裂和异裂烷基化剂,用于制备 α-异丙氧基亚甲基保护基团。此外,它还作为硫代碳酸盐转化为烯烃的中间体。
应用
2-碘丙烷(异丙基碘)被用于制备丁酸和异丁酸。
2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物(吲哚、吡啶、嘌呤、四唑、吡唑和胺)转化为对应产物。
2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物(吲哚、吡啶、嘌呤、四唑、吡唑和胺)转化为对应产物。
警示用语:
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
107.6 °F - closed cup
闪点(°C)
42 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
Journal of AOAC International, 86(4), 694-702 (2003-09-26)
An alternative liquid chromatographic (LC) method was developed and validated for the simultaneous determination of methoxyl and 2-hydroxypropoxyl substituents in hypromellose and hypromellose acetate succinate. The method uses the hydriodic acid cleavage reaction, catalyzed by adipic acid, of the substituted
The journal of physical chemistry. A, 109(30), 6659-6675 (2006-07-13)
The reaction of Cl atoms with iodoethane has been studied via a combination of laser flash photolysis/resonance fluorescence (LFP-RF), environmental chamber/Fourier transform (FT)IR, and quantum chemical techniques. Above 330 K, the flash photolysis data indicate that the reaction proceeds predominantly
Journal of bacteriology, 146(1), 133-140 (1981-04-01)
Iodopropane inhibited cell growth and methane production when Methanobacterium thermoautotrophicum, Methanobacterium formicicum, and Methanosarcina barkeri were cultured on H2-CO2. Iodopropane (40 microM) inhibited methanogenesis (30%) and growth (80%) when M. barkeri was cultured mixotrophically on H2-CO2-methanol. The addition of acetate
Development and validation of analytical procedure--control of residual 2-iodopropane in latanoprost.
Acta poloniae pharmaceutica, 67(6), 673-676 (2011-01-15)
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