148938
2-碘丙烷
contains copper as stabilizer, 99%
别名:
异丙基碘
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关于此项目
线性分子式:
(CH3)2CHI
化学文摘社编号:
分子量:
169.99
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-859-3
Beilstein/REAXYS Number:
1098244
MDL number:
产品名称
2-碘丙烷, contains copper as stabilizer, 99%
InChI key
FMKOJHQHASLBPH-UHFFFAOYSA-N
InChI
1S/C3H7I/c1-3(2)4/h3H,1-2H3
SMILES string
CC(C)I
assay
99%
form
liquid
contains
copper as stabilizer
refractive index
n20/D 1.498 (lit.)
bp
88-90 °C (lit.)
mp
−90 °C (lit.)
density
1.703 g/mL at 25 °C (lit.)
functional group
alkyl halide
iodo
Quality Level
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Application
2-碘丙烷（异丙基碘）被用于制备丁酸和异丁酸。
2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物（吲哚、吡啶、嘌呤、四唑、吡唑和胺）转化为对应产物。
2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物（吲哚、吡啶、嘌呤、四唑、吡唑和胺）转化为对应产物。
General description
2-碘丙烷是一种有机碘化合物。它通常用作均裂和异裂烷基化剂，用于制备 α-异丙氧基亚甲基保护基团。此外，它还作为硫代碳酸盐转化为烯烃的中间体。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
107.6 °F - closed cup
flash_point_c
42 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
John J Orlando et al.
The journal of physical chemistry. A, 109(30), 6659-6675 (2006-07-13)
The reaction of Cl atoms with iodoethane has been studied via a combination of laser flash photolysis/resonance fluorescence (LFP-RF), environmental chamber/Fourier transform (FT)IR, and quantum chemical techniques. Above 330 K, the flash photolysis data indicate that the reaction proceeds predominantly
W Kenealy et al.
Journal of bacteriology, 146(1), 133-140 (1981-04-01)
Iodopropane inhibited cell growth and methane production when Methanobacterium thermoautotrophicum, Methanobacterium formicicum, and Methanosarcina barkeri were cultured on H2-CO2. Iodopropane (40 microM) inhibited methanogenesis (30%) and growth (80%) when M. barkeri was cultured mixotrophically on H2-CO2-methanol. The addition of acetate
Development and validation of analytical procedure--control of residual 2-iodopropane in latanoprost.
Aleksandra Groman et al.
Acta poloniae pharmaceutica, 67(6), 673-676 (2011-01-15)
Joe Rashan et al.
Journal of AOAC International, 86(4), 694-702 (2003-09-26)
An alternative liquid chromatographic (LC) method was developed and validated for the simultaneous determination of methoxyl and 2-hydroxypropoxyl substituents in hypromellose and hypromellose acetate succinate. The method uses the hydriodic acid cleavage reaction, catalyzed by adipic acid, of the substituted
Timur Coskun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
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