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Merck
CN

148083

Sigma-Aldrich

1,1,1-三(羟甲基)丙烷

97%

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别名:
2-乙基-2-羟甲基-1,3-丙二醇, 三羟甲基丙烷
线性分子式:
CH3CH2C(CH2OH)3
CAS号:
分子量:
134.17
Beilstein:
1698309
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

4.8 (vs air)

质量水平

蒸汽压

<1 mmHg ( 20 °C)

检测方案

97%

形式

(Powder or Crystals or Granules or Chunks)

自燃温度

1301 °F

bp

159-161 °C/2 mmHg (lit.)

mp

56-58 °C (lit.)

SMILES字符串

CCC(CO)(CO)CO

InChI

1S/C6H14O3/c1-2-6(3-7,4-8)5-9/h7-9H,2-5H2,1H3

InChI key

ZJCCRDAZUWHFQH-UHFFFAOYSA-N

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应用

1,1,1-Tris(hydroxymethyl)propane was used as hydrogen bond-donating agent during triol-promoted activation of the C-F bond of benzylic fluorides. It was used in synthesis of new octanuclear manganese cluster and hyperbranched polyethers.

象形图

Health hazard

警示用语:

Warning

危险声明

危险分类

Repr. 2

WGK

WGK 1

闪点(°F)

356.0 °F

闪点(°C)

180 °C

个人防护装备

Eyeshields, Gloves, type N95 (US)


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Pier Alexandre Champagne et al.
Beilstein journal of organic chemistry, 9, 2451-2456 (2013-12-25)
Activation of the C-F bond of benzylic fluorides was achieved using 1,1,1-tris(hydroxymethyl)propane (2) as a hydrogen bond-donating agent. Investigations demonstrated that hydrogen bond-donating solvents are promoting the activation and hydrogen bond-accepting ones are hindering it. However, the reaction is best
Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate.
Rokicki G, et al.
Green Chemistry, 7(7), 529-539 (2005)
Vita Kiriliauskaitė et al.
Journal of industrial microbiology & biotechnology, 38(9), 1561-1566 (2011-02-18)
The ability of the commercial lipolytic enzyme Lipoprime 50T to catalyze the biotechnologically important synthesis of the biodegradable and environmentally acceptable trimethylolpropane (2-ethyl-2-(hydroxymethyl)-1,3-propanediol) ester of oleic acid was investigated. Simple and accurate thin-layer chromatography and computer analysis methods were used
Ruzaimah Nik Mohamad Kamil et al.
Bioresource technology, 101(15), 5877-5884 (2010-03-23)
A mathematical model describing chemical kinetics of transesterification of palm-based methyl esters with trimethylolpropane has been developed. The model was developed by utilizing nonlinear regression method, which is an efficient and powerful way to determine rate constants for both forward
M A Wright et al.
Applied and environmental microbiology, 59(4), 1072-1076 (1993-04-01)
A bacterium that was able to utilize Emkarate 1550 (E1550), a synthetic lubricant ester, as the sole source of carbon was isolated. The isolate was tentatively identified as Micrococcus roseus. The components of the E1550 ester, octanoate, decanoate, and 1,1,1-tris(hydroxymethyl)propane

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