148083
1,1,1-三(羟甲基)丙烷
97%
别名:
2-乙基-2-羟甲基-1,3-丙二醇, 三羟甲基丙烷
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关于此项目
线性分子式:
CH3CH2C(CH2OH)3
化学文摘社编号:
分子量:
134.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-074-9
Beilstein/REAXYS Number:
1698309
MDL number:
Assay:
97%
Form:
(Powder or Crystals or Granules or Chunks)
mp
56-58 °C (lit.)
functional group
hydroxyl
InChI key
ZJCCRDAZUWHFQH-UHFFFAOYSA-N
InChI
1S/C6H14O3/c1-2-6(3-7,4-8)5-9/h7-9H,2-5H2,1H3
SMILES string
CCC(CO)(CO)CO
vapor density
4.8 (vs air)
vapor pressure
<1 mmHg ( 20 °C)
assay
97%
form
(Powder or Crystals or Granules or Chunks)
autoignition temp.
1301 °F
bp
159-161 °C/2 mmHg (lit.)
Quality Level
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Application
1,1,1-Tris(hydroxymethyl)propane was used as hydrogen bond-donating agent during triol-promoted activation of the C-F bond of benzylic fluorides. It was used in synthesis of new octanuclear manganese cluster and hyperbranched polyethers.
signalword
Warning
hcodes
Hazard Classifications
Repr. 2
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
356.0 °F - Cleveland open cup
flash_point_c
180 °C - Cleveland open cup
ppe
Eyeshields, Gloves, type N95 (US)
Hyperbranched aliphatic polyethers obtained from environmentally benign monomer: glycerol carbonate.
Rokicki G, et al.
Green Chemistry, 7(7), 529-539 (2005)
Pier Alexandre Champagne et al.
Beilstein journal of organic chemistry, 9, 2451-2456 (2013-12-25)
Activation of the C-F bond of benzylic fluorides was achieved using 1,1,1-tris(hydroxymethyl)propane (2) as a hydrogen bond-donating agent. Investigations demonstrated that hydrogen bond-donating solvents are promoting the activation and hydrogen bond-accepting ones are hindering it. However, the reaction is best
Stephanie E A Gratton et al.
Journal of controlled release : official journal of the Controlled Release Society, 121(1-2), 10-18 (2007-07-24)
A novel method for the fabrication of polymeric particles on the order of tens of nanometers to several microns is described. This imprint lithographic technique called PRINT (Particle Replication In Non-wetting Templates), takes advantage of the unique properties of elastomeric
Daniel Cohn et al.
Biomaterials, 25(27), 5875-5884 (2004-06-03)
This article introduces novel biocompatible tissue adhesives that do not involve any chemical or biochemical reactions, during their application in vivo. The use of these new adhesives is based exclusively on their temperature-dependent rheological properties. Since biocompatibility and biodegradability are
Y Y Linko et al.
Journal of biotechnology, 66(1), 41-50 (1998-12-29)
The interest in the applications of biocatalysis in organic syntheses has rapidly increased. In this context, lipases have recently become one of the most studied groups of enzymes. We have demonstrated that lipases can be used as biocatalyst in the
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