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线性分子式:
CH3(CH2)5CH(OH)CH3
化学文摘社编号:
分子量:
130.23
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
EC Number:
228-213-6
Beilstein/REAXYS Number:
1719323
MDL number:
Assay:
99%
Form:
liquid
InChI key
SJWFXCIHNDVPSH-QMMMGPOBSA-N
InChI
1S/C8H18O/c1-3-4-5-6-7-8(2)9/h8-9H,3-7H2,1-2H3/t8-/m0/s1
SMILES string
CCCCCC[C@H](C)O
assay
99%
form
liquid
optical activity
[α]20/D +9.5°, neat
optical purity
ee: 98% (GLC)
Quality Level
refractive index
n20/D 1.426 (lit.)
bp
175 °C (lit.)
density
0.822 g/mL at 25 °C (lit.)
Application
(S)-(+)-2-辛醇可被用于:
- 制备5-苄氧基异邻苯二甲酸衍生物溶液,其可被用作包含有热解石墨的2D手性自组装系统。
- 作为手性模板用于研究对映选择性乙二醇酯化。
- 作为起始材料用于制备(+)-(S)-2-甲苯磺酸辛酯,一种可用于制备(−)-(R)-2-卤代和叠氮辛烷的中间体。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
168.8 °F - closed cup
flash_point_c
76 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Convenient preparation of optically active 2-halooctanes and related compounds
San Filippo Jr J and Romano LJ
The Journal of Organic Chemistry, 40(10), 1514-1515 (1975)
Development of simulation approach for two-dimensional chiral molecular self-assembly driven by hydrogen bond at the liquid/solid interface
Qin Y, et al.
Surface Science, 663, 71-80 (2017)
Effect of imprinting sol-gel immobilized lipase with chiral template substrates in esterification of (R)-(+)-and (S)-(-)-glycidol.
Furukawa S, et al.
Journal of Molecular Catalysis. B, Enzymatic, 17(1), 23-28 (2002)
Xiao-Yang Ou et al.
Journal of biotechnology, 299, 37-43 (2019-05-03)
Highly efficient asymmetric reduction of 2-octanone to (R)-2-octanol catalyzed by immobilized Acetobacter sp. CCTCC M209061 cells was achieved in a biphasic system. Bioreduction conducted in aqueous single phase buffer was limited due to poor solubility and toxicity towards cells cause
Paul Masset et al.
Cell, 182(1), 112-126 (2020-06-07)
Every decision we make is accompanied by a sense of confidence about its likely outcome. This sense informs subsequent behavior, such as investing more-whether time, effort, or money-when reward is more certain. A neural representation of confidence should originate from
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