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Merck
CN

142956

Sigma-Aldrich

2,4-二硝基苯磺酰氯

97%

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线性分子式:
(O2N)2C6H3SO2Cl
CAS号:
分子量:
266.62
Beilstein:
2147583
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

检测方案

97%

形式

solid

mp

101-103 °C (lit.)

SMILES字符串

[O-][N+](=O)c1ccc(c(c1)[N+]([O-])=O)S(Cl)(=O)=O

InChI

1S/C6H3ClN2O6S/c7-16(14,15)6-2-1-4(8(10)11)3-5(6)9(12)13/h1-3H

InChI key

SSFSNKZUKDBPIT-UHFFFAOYSA-N

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一般描述

2,4-二硝基苯磺酰氯引起糖胺发生磺化,产生 N-糖基-2,4-二硝基苯磺酰胺
可能含有高达 3.5% 的苯

应用

2,4-二硝基苯磺酰氯用于保护伯胺。它在合成 2-[((2,4-二硝基苯基)磺酰基]氨基乙酸丁酯中用作起始试剂

象形图

Health hazardCorrosion

警示用语:

Danger

危险分类

Carc. 1A - Eye Dam. 1 - Muta. 1B - Skin Corr. 1B - STOT RE 2

靶器官

Blood

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

分析证书(COA)

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Vishwanath Gaitonde et al.
Journal of carbohydrate chemistry, 31(4-6), 353-370 (2013-01-26)
The N-glycosyl-2,4-dinitrobenzenesulfonamides were accessed via benzoyl-protected β-glycosyl azides. The azides were reduced with Adams' catalyst to the corresponding amines. The glycosylamines were sulfonated with 2,4-dinitrobenzenesulfonyl chloride to form N-glycosyl-2,4-dinitrobenzenesulfonamides in moderate yields. β-Glycosyl amides were then prepared in 67 -
Rachel J Ball et al.
Artificial DNA, PNA & XNA, 1(1), 27-35 (2011-06-21)
Halogen-labelled peptide organic acid (HPOA) monomers have been synthesised and incorporated into sequence-specific peptide nucleic acid (PNA) probes. Three different types of probe have been prepared; the unmodified PNA probe, the PNA probe with a mass marker, and the PNA

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