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线性分子式:
(CH3)2NCH(OC2H5)2
化学文摘社编号:
分子量:
147.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-707-9
Beilstein/REAXYS Number:
741889
MDL number:
产品名称
N,N-二甲基甲酰胺二乙缩醛, 95%
InChI key
BWKAYBPLDRWMCJ-UHFFFAOYSA-N
InChI
1S/C7H17NO2/c1-5-9-7(8(3)4)10-6-2/h7H,5-6H2,1-4H3
SMILES string
CCOC(OCC)N(C)C
assay
95%
form
liquid
refractive index
n20/D 1.400 (lit.)
bp
130-133 °C (lit.)
density
0.859 g/mL at 25 °C (lit.)
functional group
amine
ether
Quality Level
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Application
N,N-二甲基甲酰胺二乙缩醛用于通过气相色谱法从尿液基质中测定可卡因及其主要代谢产物苯甲酰芽子碱。
General description
N,N-二甲基甲酰胺二乙缩醛与炔烃进行 Me3SiCl 介导的三组分偶联反应,生成 2,3,4,5-四取代的吡啶衍生物。
signalword
Warning
hcodes
pcodes
Hazard Classifications
Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
82.4 °F - closed cup
flash_point_c
28 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Toshiaki Sasada et al.
The Journal of organic chemistry, 73(17), 6905-6908 (2008-07-30)
We have identified a Me3SiCl-mediated three-component coupling reaction of a functionalized enamine, N,N-dimethylformamide diethyl acetal, and an internal alkyne having an electron-withdrawing group that produces 2,3,4,5-tetrasubstituted pyridine derivatives in good to excellent yields via a single-step reaction.
N C Jain et al.
Journal of forensic sciences, 22(1), 7-16 (1977-01-01)
A gas chromatographic procedure has been developed for the simultaneous determination of cocaine and benzoyl ecgonine in urine specimens. The two drugs are extracted by isopropanol/chloroform from urine samples saturated with a bisalt buffer. The organic extract is evaporated to
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