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质量水平
方案
95%
表单
liquid
折射率
n20/D 1.404 (lit.)
沸点
82 °C (lit.)
密度
1.019 g/mL at 25 °C (lit.)
官能团
chloro
ether
储存温度
2-8°C
SMILES字符串
CCOCCl
InChI
1S/C3H7ClO/c1-2-5-3-4/h2-3H2,1H3
InChI key
FCYRSDMGOLYDHL-UHFFFAOYSA-N
应用
氯甲基乙醚可用于制备：
- 6-苄基-1-(乙氧基甲基）-5-碘嘧啶-2,4(1H,3H)-二酮，其是MKC-442类似物制备中的一种关键中间体。
- 通过与乙二醛-双-[(R)-1-(2-萘基)乙基]亚胺反应生成醇的酰化催化剂1,3-双-[(R)-1-(2-萘基）乙基氯化咪唑。
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
66.2 °F - closed cup
闪点(°C)
19 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 10, 56-57 (2004-08-24)
Three Routes for the Synthesis of 6-Benzyl-1-ethoxymethyl-2, 4-dioxo-1, 2, 3, 4-tetrahydropyrimidine-5-carbaldehyde
Petersen L, et al.
Synthesis, 2001(04), 0559-0564 (2001)
K Takahashi et al.
Mutation research, 156(3), 153-161 (1985-06-01)
The mutagenic characteristics of formaldehyde on bacteria were examined. All the tester strains of Escherichia coli deficient in DNA-repair enzymes tested in the present study were significantly more sensitive to the killing effect of formaldehyde than the corresponding wild-type strain.
Chiral N-heterocyclic carbenes as asymmetric acylation catalysts
Suzuki Y, et al.
Tetrahedron, 62(2-3), 302-310 (2006)
Tadeusz J Szalaty et al.
International journal of biological macromolecules, 119, 431-437 (2018-07-29)
In this research we use ionic liquids in combination with mild process conditions to provide a selective increase in the content of carbonyl groups in the kraft lignin structure. Such modification can improve the properties of the pristine biopolymer. In
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