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Merck
CN
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文件

140910

Sigma-Aldrich

浴铜灵

greener alternative

96%

别名:

2,9-二甲基-4,7-二苯基-1,10-菲咯啉, BCP

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About This Item

经验公式（希尔记法）:
C26H20N2
CAS号:
4733-39-5
分子量:
360.45
Beilstein:
306714
EC 号:
225-240-5
MDL编号:
MFCD00004972
UNSPSC代码:
12352103
PubChem化学物质编号:
24848482
NACRES:
NA.23

检测方案

96%

形式

powder

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

279-283 °C (lit.)

λmax

~280 nm in methanol

轨道能量

HOMO 7 eV 
LUMO 3.5 eV 

OLED设备性能

ITO/CuPc/NPD/TCTA/mCP:FIrpic (6%)/BCP/LiF/Al

  • Color: blue
  • Max. EQE: 4.2 %

ITO/NPD/CBP:Ir(ppy)3/BCP/Alq3/Mg:Al
  • Color: green
  • Max. Luminance: 100000 Cd/m2
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V

ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 24529 Cd/m2
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V

ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: green
  • Max. Luminance: 207839 Cd/m2
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V

环保替代产品分类

, Enabling

SMILES字符串

Cc1cc(-c2ccccc2)c3ccc4c(cc(C)nc4c3n1)-c5ccccc5

InChI

1S/C26H20N2/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17/h3-16H,1-2H3

InChI key

STTGYIUESPWXOW-UHFFFAOYSA-N

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一般描述

我们致力于为您带来更加绿色的替代产品，这些产品遵守一项或多项绿色化学12项原则。本品属于绿色替代产品的赋能型产品，符合“节能设计”原则。有机电子传输材料具有传输电子的化学作用，可用作OLED器件的电子传输层。 点击此处以获取更多信息。

应用

浴铜灵可作为钙钛矿太阳能电池中的电子修饰层或ETL（电子传输层）间的夹层，它可用旋涂沉积法或真空热蒸发法制备。添加浴铜灵可增强有机光伏电池的能量转换效率。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H302,H413

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 4

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ （Lot或Batch）字后找到。

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What solvents can be used to dissolve Product 140910, Bathocuproine?

    This product can be dissolved in 5% pyridine to yield a dark yellow solution. It is also soluble in methanol (36 mg/100ml), isoamyl alcohol (18 mg/100 ml), dioxane (100 mg/ml), 95% ethanol (50 mg/ml) and nitrobenzene.

  5. What is the maximum absorbance wavelength for Product 140910, Bathocuproine?

    The ?max is at approximately 280 nm in methanol.

  6. What are the possible applications for Product 140910, Bathocuproine?

    It can be used for Cu(I) detection, range 0.1-10 ppm, as it is a Cu(I)-specific colorimetric reagent. It is also an organic electron transporting material.

  7. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  8. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Development of air stable polymer solar cells using an inverted gold on top anode structure.
Sahin, Yucel, et al.
Thin Solid Films, 476(2), 340-343 (2005)
Electromodulation of photoluminescence in vacuum-evaporated films of bathocuproine
Misnik, M., Falkowski, K., Mroz, W., & Stampor, W.
Chemical Physics, 410, 45-54 (2013)
Wendy A Spencer et al.
Free radical biology & medicine, 46(10), 1346-1352 (2009-02-24)
Polychlorinated biphenyls (PCBs) are toxic industrial chemicals, complete carcinogens, and efficacious tumor promoters. However, the mechanism(s) of PCB-mediated carcinogenicity remains largely undefined. One likely pathway by which these agents may play a role in carcinogenesis is the generation of oxidative
Structural templating as a route to improved photovoltaic performance in copper phthalocyanine/fullerene (C 60) heterojunctions
Sullivan, P., et al.
Applied Physics Letters, 91(23), 233114-233114 (2007)
Malin Hultberg et al.
Chemico-biological interactions, 163(3), 192-198 (2006-09-15)
Glutathione plays crucial roles in antioxidant defence and glutathione deficiency contributes to oxidative stress and may therefore play a key role in the pathogenesis of many diseases. The objectives of the present study were to evaluate the effects on glutathione
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