13929
硫氰酸苄酯
≥95.0% (GC)
别名:
硫氰化苄
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关于此项目
线性分子式:
C6H5CH2SCN
化学文摘社编号:
分子量:
149.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-144-2
Beilstein/REAXYS Number:
1859726
MDL number:
Assay:
≥95.0% (GC)
Form:
solid
InChI key
ABNDFSOIUFLJAH-UHFFFAOYSA-N
InChI
1S/C8H7NS/c9-7-10-6-8-4-2-1-3-5-8/h1-5H,6H2
SMILES string
N#CSCc1ccccc1
assay
≥95.0% (GC)
form
solid
bp
230-235 °C (lit.)
Quality Level
mp
39-41 °C
solubility
diethyl ether: soluble 0.5 g/10 mL, clear to very faintly turbid, colorless to almost colorless
functional group
phenyl, thiocyanate, thioether
storage temp.
2-8°C
General description
Benzyl thiocyanate undergoes regioselective bond dissociation during its electrochemical reduction in acetonitrile at an inert electrode. It is added to stimulate the chlortetracycline biosynthesis during industrial fermentations. It undergoes biotransformation into dibenzyl disulphide by Streptomyces aureofaciens.
Application
Benzyl thiocyanate was used to study the effects of various dietary compounds on the α-hydroxylation of N-nitrosopyrrolidine in male F344 rats in vitro.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
230.0 °F
flash_point_c
110 °C
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
危险化学品
此项目有
B S Reddy et al.
Cancer research, 47(22), 5901-5904 (1987-11-15)
The effect of feeding benzylselenocyanate (BSC) and its sulfur analogue, benzylthiocyanate (BTC), 2 wk before, during, and until 1 wk after carcinogen administration (initiation phase) on intestinal carcinogenesis induced by azoxymethane (CAS:25843-45-2) was studied in male F344 rats. Weanling rats
Effect of some benzyl thiocyanate analogs on tetracycline production.
H A Priestap
The Journal of antibiotics, 40(9), 1341-1343 (1987-09-01)
J R Nayini et al.
Nutrition and cancer, 15(2), 129-139 (1991-01-01)
The effect of dietary benzylselenocyanate (BSC) and its analogue, benzylthiocyanate (BTC), and sodium selenite during the initiation and postinitiation phases of azoxymethane (AOM)-induced intestinal carcinogenesis was studied in male F344 rats. Animals intended for initiation study were fed the high-fat
[Obstructive cholangiopathy and isothiocyanate].
D W Bleyl et al.
Die Nahrung, 35(7), 783-785 (1991-01-01)
J Fuska et al.
Letters in applied microbiology, 19(3), 124-125 (1994-09-01)
Benzyl thiocyanate, a specific stimulator of chlortetracycline biosynthesis, was transformed into dibenzyl disulphide by Streptomyces aureofaciens. The disulphide stimulated chlortetracycline production to a lesser extent than did benzyl thiocyanate.
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