138576
1-金刚烷胺
97%
别名:
1-氨基金刚烷
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关于此项目
经验公式（希尔记法）:
C10H17N
化学文摘社编号:
分子量:
151.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-201-2
Beilstein/REAXYS Number:
2204333
MDL number:
Assay:
97%
InChI key
DKNWSYNQZKUICI-CHIWXEEVSA-N
InChI
1S/C10H17N/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6,11H2/t7-,8+,9-,10-
SMILES string
NC12C[C@H]3C[C@H](C[C@H](C3)C1)C2
assay
97%
mp
206-208 °C (lit.)
solubility
1 M HCl: soluble 5%, clear to hazy, colorless to faint yellow or tan
Quality Level
Gene Information
human ... GRIN2A(2903)
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General description
金刚烷胺，又称氨基金刚烷，是金刚烷某个甲基被氨基取代形成的衍生物。常作为起始材料用于多种有机反应，例如单体合成与一锅合成金刚烷肼。
Application
1-金刚烷胺可作为一种反应物，用于合成：
- 在三乙胺存在下，与异氰酸酯反应可以制备1-金刚烷基脲。
- 在碳酸钾存在下，与氯乙酰氯反应可以制备N-(1-金刚烷基)-2-氯乙酰胺。
ppe
dust mask type N95 (US), Eyeshields, Gloves
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Jinglun Huang et al.
The Journal of organic chemistry, 72(1), 204-208 (2006-12-30)
The enantioselective Strecker reaction of N-diphenylphosphinoyl ketoimines has been achieved by use of in situ prepared chiral N,N'-dioxide catalyst from l-piperidinamide 3f and m-chloroperoxybenzoic acid (m-CPBA). Excellent yields (up to 99%) and high enantioselectivities (up to 92% ee) were obtained.
Lei Deng et al.
Nature communications, 9(1), 359-359 (2018-01-26)
Current influenza vaccines provide limited protection against circulating influenza A viruses. A universal influenza vaccine will eliminate the intrinsic limitations of the seasonal flu vaccines. Here we report methodology to generate double-layered protein nanoparticles as a universal influenza vaccine. Layered
Terminal Modification with 1-Adamantylamine to Endow Hyperbranched Polyamidoamine with Thermo-/pH-Responsive Properties.
Guo Z, et al.
Macromolecular Rapid Communications, 29(21), 1746-1751 (2008)
Adsorption isotherms and ideal selectivities of hydrogen sulfide and carbon dioxide over methane for the Si-CHA zeolite: comparison of carbon dioxide and methane adsorption with the all-silica DD3R zeolite.
Maghsoudi H, et al.
Adsorption, 19(5), 1045-1053 (2013)
Márió Gajdács et al.
Antibiotics (Basel, Switzerland), 8(4) (2019-12-22)
Background: The emergence of multidrug-resistant organisms (MDROs) is a global public health issue, severely hindering clinicians in administering appropriate antimicrobial therapy. Drug repurposing is a drug development strategy, during which new pharmacological applications are identified for already approved drugs. From
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