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质量水平
检测方案
98%
形式
powder
mp
102-106 °C (lit.)
SMILES字符串
Oc1ccc(Br)cc1C=O
InChI
1S/C7H5BrO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H
InChI key
MKKSTJKBKNCMRV-UHFFFAOYSA-N
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一般描述
5-溴水杨醛与1,2-双(4-氯-2-氨基苯氧基)乙烷反应，生成席夫碱配体1,2-双(2-(5-溴-2-羟基苯甲醛亚胺)-4-氯苯氧基)乙烷。这是合成二芳基氨基取代的N-甲基四氢salen配体的起始试剂。
5-溴水杨醛通常用于合成席夫碱和三苯基锡配合物。
5-溴水杨醛通常用于合成席夫碱和三苯基锡配合物。
应用
5-溴水杨醛可用于聚对苯二甲酸乙二醇酯（PET）薄膜和PET支架中胺定量过程中的化学衍生化。
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Salih Ilhan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 632-642 (2013-10-08)
A new Schiff base ligand was synthesized by reaction of 5-bromosalicylaldehyde with 1,2-bis(4-chloro-2-aminophenoxy)ethane. Then the Schiff base complexes were synthesized by the reaction of metal salts and the novel Schiff base. The molar conductivity properties of the complexes were studied
Investigations on the photochromic properties of 2,6-bis(5-bromo-2-hydroxybenzylidene)cyclohexanone.
L N Corîci et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 16(6), 946-953 (2017-04-27)
The network of chemical reactions of 2,6-bis(5-bromo-2-hydroxybenzylidene)cyclohexanone (BHBC) when subjected to light and different pH values has been investigated. The pH dependent species involved in the chemical network have been identified and characterized by NMR and UV-VIS spectroscopy. Direct pH
Masahito Yoshida et al.
Chemical & pharmaceutical bulletin, 68(3), 220-226 (2019-10-05)
This study demonstrates the structure-activity relationship of Col-003, a potent collagen-heat-shock protein 47 (Hsp47) interaction inhibitor. Col-003 analogues were successfully synthesized by Pd(0)-catalyzed cross-coupling reactions of 5-bromosalicylaldehyde derivatives with alkyl-metal species, and the inhibitory activities of the synthetic analogues were
Mauricio Quiroz-Guzman et al.
Dalton transactions (Cambridge, England : 2003), 40(43), 11458-11468 (2011-09-22)
A diarylamino-substituted N-methyl tetrahydrosalen (salan) ligand, (An2N)LH(2), is prepared in four steps and overall 53% yield from 5-bromosalicylaldehyde, with the key step a palladium-catalysed Hartwig-Buchwald amination of the tert-butyldimethylsilyl-protected 5-bromo-N-methylsalan ligand. Reaction of (An2N)LH(2) or its bromo analogue with Ti(O(i)Pr)(4)
Effect of Surface Modification by Ammonia Plasma on Vascular Graft: PET Film and PET Scaffold.
Oteyaka MO, et al.
Acta Physica Polonica A, 121(1), 125-125 (2012)
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