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线性分子式:
CH3OC6H4CH2OH
化学文摘社编号:
分子量:
138.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-273-6
Beilstein/REAXYS Number:
636654
MDL number:
产品名称
4-甲氧基苄醇, 98%
InChI key
MSHFRERJPWKJFX-UHFFFAOYSA-N
InChI
1S/C8H10O2/c1-10-8-4-2-7(6-9)3-5-8/h2-5,9H,6H2,1H3
SMILES string
COc1ccc(CO)cc1
assay
98%
form
solid
refractive index
n20/D 1.544 (lit.)
bp
259 °C (lit.)
mp
22-25 °C (lit.)
solubility
alcohol: freely soluble
diethyl ether: freely soluble
water: insoluble
density
1.113 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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Application
4-甲氧基苄醇用于研究4-甲氧基苄醇到对茴香醛的光催化氧化反应。
General description
4-甲氧基苄醇通常用作保护醇和酚上羟基的试剂。4-甲氧基苄醇与气相二氧化硅纳米颗粒的硅烷醇基缩合,生成改性二氧化硅纳米颗粒。它由黄素-锌(II)-轮环藤宁配合物催化发生光氧化,生成相应的苯甲醛。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1B
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Valeria B Arce et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 11(6), 1032-1040 (2012-03-17)
The knowledge of photochemical kinetics in colloidal systems is important in understanding environmental photochemistry on dispersed solid surfaces. As model materials for the chemically sorbed organic compounds present in natural environments, modified silica nanoparticles (NPs) were obtained here by condensation
Selective photocatalytic oxidation of 4-methoxybenzyl alcohol to p-anisaldehyde in organic-free water in a continuous annular fixed bed reactor.
Loddo V, et al.
International Journal of Chemical Reactor Engineering, 5(1) (2007)
Radek Cibulka et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 10(24), 6224-6231 (2004-10-16)
Flavin-zinc(II)-cyclen 10 contains a covalently linked substrate binding site (zinc(II)-cyclen) and a chromophore unit (flavin). Upon irradiation, compound 10 effectively oxidizes 4-methoxybenzyl alcohol (11-OCH3) to the corresponding benzaldehyde both in water and in acetonitrile. In the presence of air, the
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