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质量水平
方案
97%
表单
solid
沸点
288-289 °C (lit.)
mp
49-51 °C (lit.)
官能团
iodo
nitro
SMILES字符串
[O-][N+](=O)c1ccccc1I
InChI
1S/C6H4INO2/c7-5-3-1-2-4-6(5)8(9)10/h1-4H
InChI key
JXMZUNPWVXQADG-UHFFFAOYSA-N
应用
用 1-碘-2-硝基苯一步合成 2-(2-吡啶基)-3H-吲哚-3-酮 N-氧化物 。1-碘-2-硝基苯在 PEG 3400 (聚乙二醇))–Cs 2 CO 3 – 铜催化剂存在下微波活化合成 1-(2-硝基苯基)-1 H -吲哚 。
警示用语:
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
A one-step synthesis of 2-(2-Pyridyl)-3H-indol-3-one N-oxide: is it an efficient spin trap for hydroxyl radical?
The Journal of organic chemistry, 65(14), 4460-4463 (2000-07-13)
Acta chimica Slovenica, dec(4), 818-824 (2018-01-11)
An efficient, versatile and non-destructive in situ method in reaction monitoring using vibrational spectroscopy is described. A Suzuki cross-coupling reaction was monitored in which the substrate 1-iodo-2-nitrobenzene reacted with the electrophile phenylboronic acid to form the product 2-nitrobiphenyl. To hasten
PEG3400-Cs2CO3: an efficient and recyclable microwave-enhanced catalytic system for ligand-free Ullmann arylation of indole and benzimidazole.
Tetrahedron, 66(21), 3730-3735 (2010)
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