所有图片(3)
About This Item
线性分子式:
(CH3)2NCSCl
CAS号:
分子量:
123.60
Beilstein:
635823
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
表单
solid
沸点
90-95 °C/0.5 mmHg (lit.)
mp
39-43 °C (lit.)
溶解性
chloroform: soluble 100 mg/mL, clear to very slightly hazy, very faintly yellow
官能团
amine
chloro
储存温度
2-8°C
SMILES字符串
CN(C)C(Cl)=S
InChI
1S/C3H6ClNS/c1-5(2)3(4)6/h1-2H3
InChI key
PHWISQNXPLXQRU-UHFFFAOYSA-N
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应用
二甲氨基硫代甲酰氯被用于吡啶-N-氧化物的化学选择性脱氧反应。 它被用于合成 (±)-硫代胡桐素A。它被用作二甲氨基硫代甲酸酯合成中的起始试剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 2
闪点(°F)
208.4 °F - closed cup
闪点(°C)
98 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
D K Barma et al.
Organic letters, 5(25), 4755-4757 (2003-12-05)
Dimethylthiocarbamates (DMTCs), prepared from the corresponding alcohols using commercial dimethylthiocarbamoyl chloride, are spectrally simple, achiral, and nonpolar. DMTCs are moderately to highly stable to a wide range of reagents and conditions including metal hydrides, hydroboration, ylides, NaOH, HCl, organolithiums, Grignards
Journal of Heterocyclic Chemistry, 44, 487-487 (2007)
A synthesis of (?)-thia-calanolide A, its resolution and in vitro biological evaluation.
Chopade AU, et al. et al.
Arabian Journal of Chemistry (2012)
Harley D Betts et al.
Molecules (Basel, Switzerland), 25(19) (2020-10-07)
Silver(I)-based coordination polymers or metal-organic frameworks (MOFs) display useful antibacterial properties, whereby distinct materials with different bonding can afford control over the release of silver(I) ions. Such silver(I) materials are comprised of discrete secondary building units (SBUs), and typically formed
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