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方案
98%
反应适用性
reaction type: C-C Bond Formation
mp
228-230 °C (lit.)
官能团
bromo
phosphine
SMILES字符串
[Br-].BrCCC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C21H21BrP.BrH/c22-17-10-18-23(19-11-4-1-5-12-19,20-13-6-2-7-14-20)21-15-8-3-9-16-21;/h1-9,11-16H,10,17-18H2;1H/q+1;/p-1
InChI key
ZAHUZZUGJRPGKW-UHFFFAOYSA-M
应用
Reactant involved in:
- Synthesis of functionalized polyurethanes using cationic ring-opening polymerization and click chemistry
- Semipinacol rearrangement and direct arylation
- Olefination of benzaldehydes
- C-H activation / cycloisomerization
- Intramolecular dehydrobromination
- Cycloisomerizations of bromodienes and enynes
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
E W Czerwinski et al.
Acta crystallographica. Section C, Crystal structure communications, 44 ( Pt 10), 1862-1864 (1988-10-15)
C21H21BrP+.Br-, Mr = 464.2, monoclinic, P2(1)/c, a = 11.165(2), b = 10.160(2), c = 17.614(3)A, beta = 104.99(1) degree, V = 1930.08 A3, Z = 4, Dx = 1.597 g cm-3, graphite-monochromatized Cu K alpha radiation, lambda = 1.5418 A
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