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Merck
CN

135194

Sigma-Aldrich

溴代环己烷

98%

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别名:
环己基溴
经验公式(希尔记法):
C6H11Br
CAS号:
分子量:
163.06
Beilstein:
1098373
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

liquid

折射率

n20/D 1.495 (lit.)

bp

166-167 °C (lit.)

溶解性

H2O: insoluble
alcohol: soluble

密度

1.324 g/mL at 25 °C (lit.)

SMILES字符串

BrC1CCCCC1

InChI

1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2

InChI key

AQNQQHJNRPDOQV-UHFFFAOYSA-N

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一般描述

溴代环己烷的轴向构象异构体与 9,9′-联蒽基形成包合物,并表现出弱的 1,3-二轴 Cl ... H 相互作用。以石墨作为催化剂,它可参与-二甲苯的烷基化反应,生成烃

应用

通过真空紫外质谱分析阈值电离光谱法,溴代环己烷可用于研究椅基溴环己烷的赤道和轴向构象异构体的电离

象形图

Environment

危险声明

预防措施声明

危险分类

Aquatic Chronic 2

WGK

WGK 3

闪点(°F)

145.4 °F

闪点(°C)

63 °C

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Alkylation on graphite in the absence of Lewis acids.
Sereda GA.
Tetrahedron Letters, 45(39), 7265-7267 (2004)
Songhee Han et al.
The journal of physical chemistry. A, 114(37), 10005-10010 (2010-08-27)
Ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane is investigated with use of the vacuum ultraviolet mass-analyzed threshold ionization (MATI) spectroscopic technique. Two distinct ionization energies of 9.8308 ± 0.0025 and 9.8409 ± 0.0025 eV are determined for
Shinya Hirano et al.
Chemical communications (Cambridge, England), (29)(29), 3646-3648 (2005-07-20)
The axial conformers of chloro- and bromocyclohexane were isolated in a pure state as inclusion complexes with 9,9'-bianthryl, and a 1,3 diaxial Cl...H weak interaction was discovered by X-ray analysis of the axial conformer of chlorocyclohexane.
Hanumantha Rao Vutukuri et al.
Angewandte Chemie (International ed. in English), 53(50), 13830-13834 (2014-11-05)
Particle shape is a critical parameter that plays an important role in self-assembly, for example, in designing targeted complex structures with desired properties. Over the last decades, an unprecedented range of monodisperse nanoparticle systems with control over the shape of
Marjolein N van der Linden et al.
Langmuir : the ACS journal of surfaces and colloids, 31(1), 65-75 (2014-12-24)
We studied suspensions of sterically stabilized poly(methyl methacrylate) (PMMA) particles in the solvent cyclohexyl bromide (CHB; εr = 7.92). We performed microelectrophoresis measurements on suspensions containing a single particle species and on binary mixtures, using confocal microscopy to measure the

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