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质量水平
方案
98%
表单
liquid
折射率
n20/D 1.495 (lit.)
沸点
166-167 °C (lit.)
溶解性
H2O: insoluble
alcohol: soluble
密度
1.324 g/mL at 25 °C (lit.)
官能团
bromo
SMILES字符串
BrC1CCCCC1
InChI
1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2
InChI key
AQNQQHJNRPDOQV-UHFFFAOYSA-N
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一般描述
溴代环己烷的轴向构象异构体与 9，9′-联蒽基形成包合物，并表现出弱的 1，3-二轴 Cl ... H 相互作用。以石墨作为催化剂，它可参与对-二甲苯的烷基化反应，生成烃。
应用
通过真空紫外质谱分析阈值电离光谱法，溴代环己烷可用于研究椅基溴环己烷的赤道和轴向构象异构体的电离。
危险声明
预防措施声明
危险分类
Aquatic Chronic 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
145.4 °F - closed cup
闪点(°C)
63 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Songhee Han et al.
The journal of physical chemistry. A, 114(37), 10005-10010 (2010-08-27)
Ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane is investigated with use of the vacuum ultraviolet mass-analyzed threshold ionization (MATI) spectroscopic technique. Two distinct ionization energies of 9.8308 ± 0.0025 and 9.8409 ± 0.0025 eV are determined for
Alkylation on graphite in the absence of Lewis acids.
Sereda GA.
Tetrahedron Letters, 45(39), 7265-7267 (2004)
Shinya Hirano et al.
Chemical communications (Cambridge, England), (29)(29), 3646-3648 (2005-07-20)
The axial conformers of chloro- and bromocyclohexane were isolated in a pure state as inclusion complexes with 9,9'-bianthryl, and a 1,3 diaxial Cl...H weak interaction was discovered by X-ray analysis of the axial conformer of chlorocyclohexane.
Hanumantha Rao Vutukuri et al.
Angewandte Chemie (International ed. in English), 53(50), 13830-13834 (2014-11-05)
Particle shape is a critical parameter that plays an important role in self-assembly, for example, in designing targeted complex structures with desired properties. Over the last decades, an unprecedented range of monodisperse nanoparticle systems with control over the shape of
Marjolein N van der Linden et al.
Langmuir : the ACS journal of surfaces and colloids, 31(1), 65-75 (2014-12-24)
We studied suspensions of sterically stabilized poly(methyl methacrylate) (PMMA) particles in the solvent cyclohexyl bromide (CHB; εr = 7.92). We performed microelectrophoresis measurements on suspensions containing a single particle species and on binary mixtures, using confocal microscopy to measure the
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