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Merck
CN

13454

Sigma-Aldrich

N-苄基羟胺 盐酸盐

puriss., ≥99.0% (AT)

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About This Item

线性分子式:
C6H5CH2NHOH · HCl
CAS号:
分子量:
159.61
Beilstein:
507948
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

等级

puriss.

质量水平

检测方案

≥99.0% (AT)

形式

solid

mp

~105 °C
108-110 °C (lit.)

SMILES字符串

Cl.ONCc1ccccc1

InChI

1S/C7H9NO.ClH/c9-8-6-7-4-2-1-3-5-7;/h1-5,8-9H,6H2;1H

InChI key

YSNXOQGDHGUKCZ-UHFFFAOYSA-N

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应用

N-Benzylhydroxylamine hydrochloride was used in the synthesis of sugar derived nitrones. It was used as starting reagent in the synthesis of fluoro isoxazoline and isoxazolidine derivatives using flouro nitrone.

生化/生理作用

N-Benzylhydroxylamine is a potential pharmacological agent in the prevention and progression of acrolein-induced damage to the retinal pigment epithelium.

其他说明

从羰基化合物合成硝酮以及与烯烃的 [2+3]-环加成生成异噁唑烷(通用中间体);烯丙基酯的钯催化羟胺化反应。

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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T. Kawakami et al.
Bulletin of the Chemical Society of Japan, 73, 2423-2423 (2000)
B.J. Wakefield
Sci. Synth., 11, 229-229 (2002)
Ionic liquid mediated synthesis of some novel fluoro isoxazolidine and isoxazoline derivatives using N-benzyl fluoro nitrone via cycloaddition reaction and their antimicrobial activities.
Chakraborty B, et al.
Indian J. Chem. B, 52(10), 1342-1351 (2013)
R Herrera et al.
The Journal of organic chemistry, 66(4), 1252-1263 (2001-04-21)
Captodative olefins 1-acetylvinyl carboxylates proved to be highly regioselective dipolarophiles in 1,3-dipolar cycloadditon to propionitrile oxide, arylphenylnitrile imines, diazoalkanes, and nitrones to yield the corresponding 5-substituted heterocycles. The addition of the latter was also stereoselective, being slightly susceptible to steric
Synthesis of trihydroxy quinolizidine alkaloids: 1, 3-addition reaction of allylmagnesium bromide to a sugar nitrone.
Dhavale DD, et al.
Tetrahedron, 60(13), 3009-3016 (2004)

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