所有图片(1)
About This Item
线性分子式:
C6H5CH2NHOH · HCl
CAS号:
分子量:
159.61
Beilstein:
507948
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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等级
puriss.
质量水平
方案
≥99.0% (AT)
表单
solid
mp
~105 °C
108-110 °C (lit.)
官能团
amine
phenyl
SMILES字符串
Cl.ONCc1ccccc1
InChI
1S/C7H9NO.ClH/c9-8-6-7-4-2-1-3-5-7;/h1-5,8-9H,6H2;1H
InChI key
YSNXOQGDHGUKCZ-UHFFFAOYSA-N
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应用
N-Benzylhydroxylamine hydrochloride was used in the synthesis of sugar derived nitrones. It was used as starting reagent in the synthesis of fluoro isoxazoline and isoxazolidine derivatives using flouro nitrone.
生化/生理作用
N-Benzylhydroxylamine is a potential pharmacological agent in the prevention and progression of acrolein-induced damage to the retinal pigment epithelium.
其他说明
从羰基化合物合成硝酮以及与烯烃的 [2+3]-环加成生成异噁唑烷（通用中间体）；烯丙基酯的钯催化羟胺化反应。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
T. Kawakami et al.
Bulletin of the Chemical Society of Japan, 73, 2423-2423 (2000)
R Herrera et al.
The Journal of organic chemistry, 66(4), 1252-1263 (2001-04-21)
Captodative olefins 1-acetylvinyl carboxylates proved to be highly regioselective dipolarophiles in 1,3-dipolar cycloadditon to propionitrile oxide, arylphenylnitrile imines, diazoalkanes, and nitrones to yield the corresponding 5-substituted heterocycles. The addition of the latter was also stereoselective, being slightly susceptible to steric
B.J. Wakefield
Sci. Synth., 11, 229-229 (2002)
S. Murahashi et al.
Tetrahedron Letters, 29, 2973-2973 (1988)
Ionic liquid mediated synthesis of some novel fluoro isoxazolidine and isoxazoline derivatives using N-benzyl fluoro nitrone via cycloaddition reaction and their antimicrobial activities.
Chakraborty B, et al.
Indian J. Chem. B, 52(10), 1342-1351 (2013)
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