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Merck
CN

133035

2-甲基丙烯醛

95%

别名:

异丁烯醛

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线性分子式:
H2C=C(CH3)CHO
化学文摘社编号:
分子量:
70.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-150-1
Beilstein/REAXYS Number:
1209258
MDL number:
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产品名称

2-甲基丙烯醛, 95%

InChI key

STNJBCKSHOAVAJ-UHFFFAOYSA-N

InChI

1S/C4H6O/c1-4(2)3-5/h3H,1H2,2H3

SMILES string

[H]C(=O)C(C)=C

vapor density

2.4 (vs air)

vapor pressure

121 mmHg ( 20 °C)
13.44 psi ( 55 °C)
5.35 psi ( 20 °C)

assay

95%

form

liquid

refractive index

n20/D 1.416 (lit.)

bp

68-70 °C (lit.)

mp

−81 °C (lit.)

density

0.85 g/mL at 25 °C (lit.)

functional group

aldehyde

storage temp.

2-8°C

Quality Level

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Application

甲基丙烯醛用于研究烃氧化产物和萜烯氧化产物甲基丙烯醛对人眨眼频率的影响,影响水平在十亿分之几。它还用于测定氯原子与丙烯醛、甲基丙烯醛和甲基乙烯基酮反应的速率常数和产物

General description

甲基丙烯醛在300℃下在杂多酸催化剂(主要是 12-钼磷酸)催化下氧化生成甲基丙烯酸 。它是异戊二烯氧化的主要产物

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

5.0 °F - closed cup

flash_point_c

-15 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Isoprene and its oxidation products methyl vinyl ketone, methacrolein, and isoprene related peroxides measured online over the tropical rain forest of Surinam in March 1998.
Warneke C, et al.
Journal of Atmospheric Chemistry, 38(2), 167-185 (2001)
The reactions of atomic chlorine with acrolein, methacrolein and methyl vinyl ketone.
Canosa-Mas CE, et al.
Physical Chemistry Chemical Physics, 3(15), 3075-3084 (2001)
Eeva K Kemppainen et al.
Organic letters, 14(4), 1086-1089 (2012-02-03)
Enantioselective iminium-catalyzed reactions with acrolein and methacrolein are rare. A catalytic enantioselective Mukaiyama-Michael reaction that readily accepts acrolein or methacrolein as substrates, affording the products in good yields and 91-97% ee, is presented. As an application of the methodology, an
Denise Biagini et al.
Talanta, 200, 145-155 (2019-05-01)
When working with humid gaseous samples, the amount of water vapour collected in a needle trap along with volatile analytes may vary from sample to sample and decrease during the storage. This has a major impact on desorption efficiency and
Henrik G Kjaergaard et al.
The journal of physical chemistry. A, 116(24), 5763-5768 (2012-03-29)
We investigate the oxidation of methacryloylperoxy nitrate (MPAN) and methacrylicperoxy acid (MPAA) by the hydroxyl radical (OH) theoretically, using both density functional theory [B3LYP] and explicitly correlated coupled cluster theory [CCSD(T)-F12]. These two compounds are produced following the abstraction of

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