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133035

2-甲基丙烯醛

Name: 2-甲基丙烯醛
Brand: ALDRICH

95%

别名:

异丁烯醛

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关于此项目

线性分子式:

H₂C=C(CH₃)CHO

化学文摘社编号:

78-85-3

分子量:

70.09

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24848091

EC Number:

201-150-1

Beilstein/REAXYS Number:

1209258

MDL number:

MFCD00006974

Assay:

95%

Form:

liquid

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属性

vapor density

2.4 (vs air)

Quality Level

100

vapor pressure

121 mmHg ( 20 °C), 13.44 psi ( 55 °C), 5.35 psi ( 20 °C)

assay

95%

form

liquid

refractive index

n20/D 1.416 (lit.)

bp

68-70 °C (lit.)

mp

−81 °C (lit.)

density

0.85 g/mL at 25 °C (lit.)

functional group

aldehyde

storage temp.

2-8°C

SMILES string

[H]C(=O)C(C)=C

InChI

1S/C4H6O/c1-4(2)3-5/h3H,1H2,2H3

InChI key

STNJBCKSHOAVAJ-UHFFFAOYSA-N

说明

General description

甲基丙烯醛在300℃下在杂多酸催化剂（主要是 12-钼磷酸）催化下氧化生成甲基丙烯酸。它是异戊二烯氧化的主要产物。

Application

甲基丙烯醛用于研究烃氧化产物和萜烯氧化产物甲基丙烯醛对人眨眼频率的影响，影响水平在十亿分之几。它还用于测定氯原子与丙烯醛、甲基丙烯醛和甲基乙烯基酮反应的速率常数和产物。

pictograms

GHS02,GHS06,GHS08,GHS05,GHS09

signalword

Danger

hcodes

H225,H301 + H311,H314,H330,H341,H410

pcodes

P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Muta. 2 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

5.0 °F - closed cup

flash_point_c

-15 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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Computational evaluation of enantioselective Diels-Alder reactions mediated by Corey's cationic oxazaborolidine catalysts.

Michael N Paddon-Row et al.

The Journal of organic chemistry, 74(2), 861-868 (2008-12-11)

The cationic oxazaborolidine-catalyzed Diels-Alder reactions of butadiene and a series of five dienophiles have been studied using density functional theory (B3LYP/6-31G(d)). In each case, the computational results successfully reproduce the experimentally observed sense of stereoinduction and enantiomeric ratio. The computed

Effects of methacrolein on the respiratory tract in mice.

S T Larsen et al.

Toxicology letters, 114(1-3), 197-202 (2000-03-14)

The acute respiratory effects of airborne exposure to methacrolein were studied in a recent refinement of the standard test method with mice (ASTM, 1984. American Society for Testing and Materials, Philadelphia). Irritation of the upper respiratory tract caused a concentration-dependent

Catalysis by heteropoly compounds: IV. Oxidation of methacrolein to methacrylic acid over 12-molybdophosphoric acid.

Konishi Y, et al.

J. Catal., 77(1), 169-179 (1982)

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全球贸易项目编号

货号	GTIN
133035-25ML	04061838729309
133035-5ML	04061838729316