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蒸汽密度
2.41 (vs air)
蒸汽压
32 mmHg ( 20 °C)
方案
90%
自燃温度
320 °F
expl. lim.
19.5 %
杂质
8-10% water
折射率
n20/D 1.4362 (lit.)
沸点
104 °C (lit.)
mp
−76 °C (lit.)
溶解性
water: soluble 18.1g/100g at 20 °C
water: soluble 19.2g/100g at 5 °C
密度
0.846 g/mL at 25 °C (lit.)
SMILES字符串
[H]\C(C)=C(\[H])C([H])=O
InChI
1S/C4H6O/c1-2-3-4-5/h2-4H,1H3/b3-2+
InChI key
MLUCVPSAIODCQM-NSCUHMNNSA-N
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一般描述
Crotonaldehyde on hydrogenation over Pt/SiO2 and Pt/TiO2 catalysts yields butyraldehyde and crotylalcohol depending on the size of the Pt particles and the promotion by surface oxides. It forms adducts with oligodeoxynucleotides containing 1,N2-deoxyguanosine residues and forms crosslinks with the tetrapeptide Lys-Trp-Lys-Lys.
应用
Crotonaldehyde was used to study the kinetics of the reaction of acrolein,crotonaldehyde and pivalaldehyde with Cl atoms.
法规信息
新产品
Andrew J Kurtz et al.
The Journal of biological chemistry, 278(8), 5970-5976 (2002-12-28)
DNA-protein cross-links (DPCs) are formed upon exposure to a variety of chemical and physical agents and pose a threat to genomic integrity. In particular, acrolein and related aldehydes produce DPCs, although the chemical linkages for such cross-links have not been
Structure Sensitivity of the Hydrogenation of Crotonaldehyde over Pt/SiO2 and Pt/TiO2.
Englisch M, et al.
J. Catal., 166(1), 25-35 (1997)
Reactions of acrolein, crotonaldehyde and pivalaldehyde with Cl atoms: structure-activity relationship and comparison with OH and NO3 reactions.
Ullerstam M, et al.
Physical Chemistry Chemical Physics, 3(6), 986-992 (2001)
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