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蒸汽压
0.4 mmHg ( 20 °C)
质量水平
检测方案
99%
形式
liquid
折射率
n20/D 1.49 (lit.)
bp
92-93 °C/18 mmHg (lit.)
密度
0.931 g/mL at 25 °C (lit.)
SMILES字符串
NC1CCCCC1N
InChI
1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2
InChI key
SSJXIUAHEKJCMH-UHFFFAOYSA-N
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一般描述
1,2-二氨基环己烷与同手性化合物以及外消旋形式的 反式 -1,2-二氨基环己烷与对苯二甲醛发生非模板反应，生成 (3 + 3)-环缩合分子三角形 。它作为配体与有机锡形成络合物，作为金属类抗肿瘤药物具有潜在的应用价值 。
应用
将 1，2-二氨基环己烷用于手性钌 (Ⅳ) 氧配合物的合成 。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
WGK
WGK 1
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
(3+ 3)-Cyclocondensation of the enantiopure and racemic forms of trans-1, 2-diaminocyclohexane with terephthaldehyde. Formation of diastereomeric molecular triangles and their stereoselective solid-state stacking into microporous chiral columns.
Chadim M, et al.
Tetrahedron Asymmetry, 12(1), 127-133 (2001)
J J Bonire et al.
Journal of inorganic biochemistry, 83(2-3), 217-221 (2001-03-10)
Platinum compounds containing the ligand 1,2-diaminocyclohexane (DACH) such as tetraplatin [PtCl4(DACH)] have been found to be active in cisplatin-resistant tumour models. In an attempt to develop novel metal-based drugs with a different therapeutic profile to cisplatin, we have synthesised a
Chiral ruthenium (IV)-oxo complexes. Structure, reactivities of [Ru (terpy)(Nn N) O]2+Nn N= N, N, N', N'-tetramethyl-1, 2-diaminocyclohexane) and [Ru (Me3 tacn)(cbpy) O]2+ (cbpy=(-)-3, 3'-[(4 S-trans)-1, 3-dioxolane-4, 5-dimethyl]-2, 2'-bipyridine).
Cheng WC, et al.
Inorgorganica Chimica Acta, 242(1), 105-113 (1996)
Ran Feng et al.
Dalton transactions (Cambridge, England : 2003), 42(6), 2130-2145 (2012-11-29)
In this paper, the origins of enantioselectivity in asymmetric ketone hydrogenation catalyzed by RuH(2)(binap)(cydn) (cydn = trans-1,2-diaminocyclohexane) were discussed. Fifteen substrates involving aromatic, heteroaromatic, olefinic and dialkyl prochiral ketones were used to probe the catalytic mechanism and find an effective
Hidekazu Yamada et al.
Journal of the American Chemical Society, 134(17), 7250-7253 (2012-04-18)
Optically active amidine dimer strands having a variety of chiral and achiral linkers with different stereostructures are synthesized and used as templates for diastereoselective imine-bond formations between two achiral carboxylic acid monomers bearing a terminal aldehyde group and racemic 1,2-cyclohexanediamine
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