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方案
99%
表单
liquid
溶解性
water: soluble 112 g/L at 20 °C
一般描述
Triethylamine trihydrofluoride is a non-corrosive reagent. It is a promising source of fluorine and is widely employed in various benzylic fluorination reactions.
应用
Triethylamine trihydrofluoride (TREAT-HF) may be employed as a fluorinating reagent for the following studies:
- Microwave-assisted transformation of dichloromethyl- and trichloromethyl substrates to the corresponding fluoro analogs.
- Preparation of 9-(2,3-dideoxy-2-fluoro-β-D-threo-pentofuranosyl)adenine.
- Synthesis of various fluorinated compounds.
- Preparation of fluoroamines.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
12.2 °F - closed cup
闪点(°C)
-11 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Wei Liu et al.
Angewandte Chemie (International ed. in English), 52(23), 6024-6027 (2013-04-26)
An efficient protocol for the selective fluorination of benzylic C-H bonds is described. The process is catalyzed by manganese salen complexes and uses nucleophilic fluorine sources, such as triethylamine trihydrofluoride and KF. Reaction rates are sufficiently high (30 min) to
Asymmetric Synthesis of Fluoroamines from Chiral Aziridines.
Park H, et al.
Bull. Korean Chem. Soc., 35, 699-700 (2014)
Improved synthesis of 9-(2, 3-dideoxy-2-fluoro-β-D-threo-pentofuranosyl) adenine (FddA) using triethylamine trihydrofluoride.
Takamatsu S, et al.
Tetrahedron Letters, 42(12), 2321-2324 (2001)
Microwave-assisted aliphatic fluorine-chlorine exchange using triethylamine trihydrofluoride (TREAT-HF).
Kremsner JM, et al.
Tetrahedron Letters, 50(26), 3665-3668 (2009)
Marcus Gry Björklund et al.
Nucleic acids research, 36(4), 1334-1342 (2008-01-12)
DNA microarray technology has evolved dramatically in recent years, and is now a common tool in researchers' portfolios. The scope of the technique has expanded from small-scale studies to extensive studies such as classification of disease states. Technical knowledge regarding
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