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Merck
CN

13112

powder, ≥99%

别名:

镁元素

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关于此项目

经验公式(希尔记法):
Mg
化学文摘社编号:
分子量:
24.31
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
38110201
UNSPSC Code:
12141502
EC Number:
231-104-6
MDL number:
Beilstein/REAXYS Number:
4948473
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产品名称

镁, powder, ≥99%

Quality Level

InChI key

FYYHWMGAXLPEAU-UHFFFAOYSA-N

InChI

1S/Mg

SMILES string

[Mg]

vapor pressure

1 mmHg ( 621 °C)

assay

≥99%

form

powder

autoignition temp.

950 °F

reaction suitability

reagent type: reductant

resistivity

4.46 μΩ-cm, 20°C

impurities

≤0.05% insoluble in HCl

bp

1090 °C (lit.)

mp

648 °C (lit.)

density

1.74 g/mL at 25 °C (lit.)

cation traces

Fe: ≤500 mg/kg

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Analysis Note

外观:银灰色

Application

镁(粉)可用作还原剂以合成:
  • 钛合金氢化物粉末,通过氢气气氛下还原升级钛渣(UGS)。      
  • 通过球磨法从赤铁矿(α-Fe2O3)制备超细金属铁(bcc-Fe)粉。

还可用作还原剂,用于钌(III)络合物催化原子转移自由基加成(ATRA)和环化(ATRC)反应。镁不能产生自由基,但能生成和再生具有催化活性的钌(II)。

pictograms

Flame

signalword

Danger

Hazard Classifications

Flam. Sol. 1 - Self-heat. 1 - Water-react 2

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Hyperbranched polyalkenylsilanes by hydrosilylation with platinum catalysts. I. Polymerization
Drohmann C, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 38(4), 741-751 (2000)
Ultrafine spinel powders by flame spray pyrolysis of a magnesium aluminum double alkoxide.
Bickmore CR, et al.
Journal of the American Chemical Society, 79(5), 1419-1423 (1996)
Katrin Thommes et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(24), 6899-6907 (2007-06-05)
A new catalytic procedure for atom-transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl(2)Cp*(PPh3)] (Cp*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild conditions with high efficiency. In most
Uttley C.
Magnesium, 4-4 null
Jochen Halfar et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(49), 19737-19741 (2013-11-20)
Northern Hemisphere sea ice has been declining sharply over the past decades and 2012 exhibited the lowest Arctic summer sea-ice cover in historic times. Whereas ongoing changes are closely monitored through satellite observations, we have only limited data of past

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