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应用
镁(粉)可用作还原剂以合成:
还可用作还原剂,用于钌(III)络合物催化原子转移自由基加成(ATRA)和环化(ATRC)反应。镁不能产生自由基,但能生成和再生具有催化活性的钌(II)。
- 钛合金氢化物粉末,通过氢气气氛下还原升级钛渣(UGS)。
- 通过球磨法从赤铁矿(α-Fe2O3)制备超细金属铁(bcc-Fe)粉。
还可用作还原剂,用于钌(III)络合物催化原子转移自由基加成(ATRA)和环化(ATRC)反应。镁不能产生自由基,但能生成和再生具有催化活性的钌(II)。
分析说明
外观:银灰色
警示用语:
Danger
危险声明
危险分类
Flam. Sol. 1 - Self-heat. 1 - Water-react 2
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
nwg
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
监管及禁止进口产品
Katrin Thommes et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(24), 6899-6907 (2007-06-05)
A new catalytic procedure for atom-transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl(2)Cp*(PPh3)] (Cp*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild conditions with high efficiency. In most
Ultrafine spinel powders by flame spray pyrolysis of a magnesium aluminum double alkoxide.
Bickmore CR, et al.
Journal of the American Chemical Society, 79(5), 1419-1423 (1996)
Hyperbranched polyalkenylsilanes by hydrosilylation with platinum catalysts. I. Polymerization
Drohmann C, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 38(4), 741-751 (2000)
Uttley C.
Magnesium, 4-4 null
Shuvendu Biswas et al.
Nature chemistry, 5(7), 613-620 (2013-06-22)
The development of nanocarriers that selectively release guest molecules on sensing a particular biological signal is being actively pursued in nanomedicine for diagnostic and therapeutic purposes. Here we report a protein-based nanocarrier that opens in the presence of intracellular adenosine-5'-triphosphate
商品
Mechanochemical Effect of Severe Plastic Deformations: Metal Alloys, Hydrides and Molecular Solids
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