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About This Item
经验公式（希尔记法）:
C15H12O4
CAS号:
分子量:
256.25
Beilstein:
2131052
EC 号:
MDL编号:
UNSPSC代码:
12352108
PubChem化学物质编号:
NACRES:
NA.22
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方案
≥98.0% (T)
mp
126-129 °C
应用
peptide synthesis
官能团
carboxylic acid
ester
phenyl
SMILES字符串
OC(=O)c1ccccc1COC(=O)c2ccccc2
InChI
1S/C15H12O4/c16-14(17)13-9-5-4-8-12(13)10-19-15(18)11-6-2-1-3-7-11/h1-9H,10H2,(H,16,17)
InChI key
QDENBWUYSUBCID-UHFFFAOYSA-N
应用
2-(Benzoyloxymethyl)benzoic acid can be used to synthesize:
- 2-(Benzoyloxymethyl)benzoyl chloride (BMBC) by reacting with oxalyl chloride. BMBC intermediate is utilized for the preparation of dimethyl 2-(benzoyloxymethyl)benzoylphosphonate by treating with trimethyl phosphite.
- 2-Benzoyloxymethylbenzoic acid 4-nitrophenyl ester by reaction with 4-nitrophenol via 2-benzoyloxymethylbenzoyl chloride formation.
- 2-[2-(Benzoyloxymethyl)benzamido]acetamide by treating with glycinamide and followed by addition of PCl3.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Cyclisation reactions of 2-substituted benzoylphosphonates with trialkyl phosphites via nucleophilic attack on a carbonyl-containing ortho substituent
Cheong Y-K, et al.
Tetrahedron, 64(10), 2329-2338 (2008)
2-Acyloxymethylbenzoic acids. Novel amine protective functions providing amides with the lability of esters
Cain BF
The Journal of Organic Chemistry, 41(11), 2029-2031 (1976)
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