130001
1-甲基哌嗪
99%
别名:
N-Methylpiperazine
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关于此项目
经验公式（希尔记法）:
C5H12N2
化学文摘社编号:
分子量:
100.16
Beilstein:
102724
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
蒸汽密度
3.5 (vs air)
质量水平
方案
99%
表单
liquid
折射率
n20/D 1.466 (lit.)
沸点
138 °C (lit.)
密度
0.903 g/mL at 25 °C (lit.)
SMILES字符串
CN1CCNCC1
InChI
1S/C5H12N2/c1-7-4-2-6-3-5-7/h6H,2-5H2,1H3
InChI key
PVOAHINGSUIXLS-UHFFFAOYSA-N
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一般描述
1-甲基哌嗪是一种杂环二胺，在有机合成中用作多功能合成砌块和中间体。
应用
1-甲基哌嗪用作制备分子印迹微球（MIM）的模拟模板。它还用于由 1，4-二氮杂环己烷衍生物制备双官能强阴离子交换固定相。
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1B
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
88.7 °F - closed cup
闪点(°C)
31.5 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Juxiang Ruan et al.
Journal of chromatography. A, 1297, 77-84 (2013-06-01)
This paper reports the preparation of a novel, silica-based, strong anion-exchange stationary phase from a 1,4-diazacyclohexane derivative. To prepare the difunctional strong anion-exchange stationary phase, activated silica beads were first bonded with 3-chloropropyltriethoxysilane and then reacted with 1-methylpiperazine followed by
Hongyuan Yan et al.
The Analyst, 137(12), 2884-2890 (2012-05-04)
A highly selective molecularly imprinted solid-phase extraction (MISPE) combined with liquid chromatography-ultraviolet detection was developed for the simultaneous isolation and determination of four plant hormones including indole-3-acetic acid (IAA), indole-3-propionic acid (IPA), indole-3-butyric acid (IBA) and 1-naphthaleneacetic acid (NAA) in
H Welinder et al.
International archives of allergy and applied immunology, 79(3), 259-262 (1986-01-01)
The presence of specific IgE antibodies against conjugates between human serum albumin and piperazine, a compound previously known to cause occupational asthma, and N-methyl-piperazine, respectively, was demonstrated by RAST, RAST inhibition and skin prick tests in 2 asthmatic subjects occupationally
E Gavathiotis et al.
Nucleic acids research, 28(3), 728-735 (2000-01-19)
The solution structure of the dodecamer duplex d(CTTTTGCAAAAG)(2)and its 2:1 complex with the bis -benzimidazole Hoechst 33258 has been investigated by NMR and NOE-restrained molecular dynamics (rMD) simulations. Drug molecules are bound in each of the two A-tracts with the
Olesya A Troshina et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(21), 5569-5577 (2006-06-07)
An oxidative radical photoaddition of mono N-substituted piperazines to [60]fullerene was systematically investigated. Reactions of C60 with piperazines bearing bulky electron-withdrawing groups (2-pyridyl, 2-pyrimidinyl) were found to be the most selective and yielded C60(amine)4O as major products along with small
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