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质量水平
检测方案
98%
形式
liquid
折射率
n20/D 1.487 (lit.)
bp
181 °C (lit.)
密度
1.179 g/mL at 25 °C (lit.)
SMILES字符串
COC(=O)c1ccco1
InChI
1S/C6H6O3/c1-8-6(7)5-3-2-4-9-5/h2-4H,1H3
InChI key
HDJLSECJEQSPKW-UHFFFAOYSA-N
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应用
2-糠酸甲酯（呋喃-2-羧酸甲酯，焦木酸甲酯）被用于合成顺式融合的5-氧呋喃[2,3-b]呋喃。它也可用于倍半萜内酯的制备。
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
163.4 °F
闪点(°C)
73 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Roland Weisser et al.
Organic letters, 7(24), 5353-5356 (2005-11-18)
[structure: see text] A short and enantioselective synthesis of cis-fused 5-oxofuro[2,3-b]furans, being found in many spongiane diterpenoid natural products, is reported starting from inexpensive methyl 2-furoate. Moreover, the acid-catalyzed rearrangement of the furo[2,3-b]furan framework A to B is observed for
Andreas Kreuzer et al.
Organic letters, 15(13), 3420-3423 (2013-06-26)
The first total synthesis of either enantiomer of Arteludovicinolide A and their biological evaluation is reported, featuring a new strategy for the asymmetric construction of γ-butyrolactones with stereogenic side chains in the 4-position. Starting from the renewable resource methyl 2-furoate
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