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质量水平
方案
97%
表单
solid
mp
172-175 °C (lit.)
荧光
λex 367 nm; λem 445 nm (α-keto acid adduct)
SMILES字符串
NC(=O)CC(N)=O
InChI
1S/C3H6N2O2/c4-2(6)1-3(5)7/h1H2,(H2,4,6)(H2,5,7)
InChI key
WRIRWRKPLXCTFD-UHFFFAOYSA-N
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一般描述
丙二酰胺衍生物是通过异氰酸酯、Meldrum′s酸、芳叉丙二腈和CH 2 Cl 2 中两个胺分子的一锅五组分缩合反应产生的。
应用
离子液体萃取剂用于从硝酸介质中萃取铕（iii）等三价稀土离子 。
储存分类代码
11 - Combustible Solids
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Suban K Sahoo et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 63(3), 574-586 (2005-07-19)
A new dipodal ligand, N,N'-bis{2-[(2-hydroxybenzylidine)amino]ethyl}malonamide (BHAEM) was synthesized by Schiff base condensation of N,N'-bis(2-aminoethyl)malonamide with two equivalent of salicylaldehyde and characterized on the basis of elemental analyses and various spectral (UV-vis, IR, (1)H NMR and (13)C NMR) data. The complexation
Alok Rout et al.
Dalton transactions (Cambridge, England : 2003), 43(4), 1862-1872 (2013-11-22)
A new non-fluorinated malonamide-based ionic liquid extractant was synthesized and investigated for the extraction behavior of europium(III) and other trivalent rare-earth ions from nitric acid medium. The extractant was the functionalized ionic liquid trihexyl(tetradecyl)phosphonium N,N,N',N'-tetra(2-ethylhexyl)malonate, [P66614][MA], and it was used
Mi-Hyun Kim et al.
Organic letters, 12(12), 2826-2829 (2010-05-27)
A new enantioselective synthetic method of (-)-paroxetine is reported. (-)-Paroxetine could be obtained in 15 steps (95% ee and 9.1% overall yield) from N,N-bis(p-methoxyphenyl)malonamide tert-butyl ester via the enantioselective phase-transfer catalytic alkylation and the diastereoselective Michael addition as the key
Syntheses and antiinflammatory activity of malonamic acid, malonamate and malonamide derivatives of some heterocyclic compounds.
T Katagi et al.
Chemical & pharmaceutical bulletin, 33(11), 4878-4888 (1985-11-01)
Ranjeet A Dhokale et al.
Organic letters, 14(15), 3994-3997 (2012-07-27)
A facile, fluoride-induced transition-metal-free chemoselective α-arylation of β-dicarbonyl compounds (malonamide esters) at room temperature using aryne intermediates has been demonstrated. Selective mono- or diarylation and generation of a quaternary benzylic stereocenter have also been achieved. The methodology will be highly
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