129216
环己乙炔
98%
别名:
乙炔基环己烷
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关于此项目
线性分子式:
C6H11C≡CH
化学文摘社编号:
分子量:
108.18
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-236-6
Beilstein/REAXYS Number:
1815535
MDL number:
产品名称
环己乙炔, 98%
InChI key
SSDZYLQUYMOSAK-UHFFFAOYSA-N
InChI
1S/C8H12/c1-2-8-6-4-3-5-7-8/h1,8H,3-7H2
SMILES string
C#CC1CCCCC1
assay
98%
form
liquid
refractive index
n20/D 1.4540 (lit.)
bp
130-132 °C (lit.)
density
0.828 g/mL at 25 °C (lit.)
Quality Level
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Application
环己基乙炔（乙炔基环己烷）用于制备 [Os [(E)-CH = CHR] (= C = C = CPh2) (CH3CN) 2 (P (i) Pr3) 2] BF4 (R = Ph,Cy) 。
General description
环己基乙炔（乙炔基环己烷）与肝微粒体孵育时介导 NADPH 依赖性细胞色素 P-450 损失 。
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
64.4 °F - closed cup
flash_point_c
18 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Self-catalyzed inactivation of hepatic cytochrome P-450 by ethynyl substrates.
P R Ortiz de Montellano et al.
The Journal of biological chemistry, 255(12), 5578-5585 (1980-06-25)
Tamara Bolaño et al.
Journal of the American Chemical Society, 128(12), 3965-3973 (2006-03-23)
Treatment in acetonitrile at -30 C of the hydride-alkenylcarbyne complex [OsH([triple bond]CCH=CPh2)(CH3CN)2(P(i)Pr3)2][BF4]2 (1) with (t)BuOK produces the selective deprotonation of the alkenyl substituent of the carbyne and the formation of the bis-solvento hydride-allenylidene derivative [OsH(=C=C=CPh2)(CH3CN)2(P(i)Pr3)2]BF4 (2), which under carbon monoxide
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