126179
9,10-二氢蒽
97%
别名:
Dihydroanthracene
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关于此项目
经验公式（希尔记法）:
C14H12
化学文摘社编号:
分子量:
180.25
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-336-1
Beilstein/REAXYS Number:
1364575
MDL number:
产品名称
9,10-二氢蒽, 97%
InChI key
WPDAVTSOEQEGMS-UHFFFAOYSA-N
InChI
1S/C14H12/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h1-8H,9-10H2
SMILES string
C1c2ccccc2Cc3ccccc13
assay
97%
form
solid
bp
312 °C (lit.)
mp
103-107 °C (lit.)
density
0.88 g/mL at 25 °C (lit.)
Quality Level
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Application
9，10-二氢蒽（DHA）长期用于在研究中评估 MeCN 中价离域铁络合物的夺氢能力。
General description
在 [7H] 苯并蒽催化剂存在下，9，10-二氢蒽可引起 C60 和 C70 的转移氢化。在作为氧化剂的分子氧和作为二甲苯中的促进剂的活性炭存在下，它被氧化芳构化为相应的蒽。
Genqiang Xue et al.
Proceedings of the National Academy of Sciences of the United States of America, 104(52), 20713-20718 (2007-12-21)
Intermediate Q, the methane-oxidizing species of soluble methane monooxygenase, is proposed to have an [Fe(IV)(2)(mu-O)(2)] diamond core. In an effort to obtain a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc(+/0)) has been performed in
Nirupama Singh et al.
Journal of inorganic biochemistry, 197, 110674-110674 (2019-05-21)
Developing coordination complexes of earth abundant metals that can perform substrate oxidations under benign conditions is an ongoing challenge. Herein, the reactivity of two mononuclear Cu-complexes toward the oxidant H2O2 is reported. Both complexes displayed ligand oxidation upon reaction with
[7H] Benzanthrone, a catalyst for the transfer hydrogenation of C60 and C70 by 9, 10-dihydroanthracene.
Gerst M, et al.
Tetrahedron Letters, 34(48), 7729-7732 (1993)
Natsuki Nakamichi et al.
The Journal of organic chemistry, 68(21), 8272-8273 (2003-10-11)
Substituted 9,10-dihydroanthracenes were oxidatively aromatized to the corresponding anthracenes effectively by using molecular oxygen as an oxidant and activated carbon (Darco KB, Aldrich, Inc.) as a promoter in xylene.
Pengfei Sun et al.
Small (Weinheim an der Bergstrasse, Germany), 16(3), e1906462-e1906462 (2019-12-24)
Lithium primary batteries are still widely used in military, aerospace, medical, and civilian applications despite the omnipresence of rechargeable Li-ion batteries. However, these current primary chemistries are exclusively based on inorganic materials with high cost, low energy density or severe
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