蒸汽密度
5 (vs air)
质量水平
检测方案
97%
折射率
n20/D 1.553 (lit.)
bp
121-123 °C/15 mmHg (lit.)
mp
7-9 °C (lit.)
密度
1.058 g/mL at 25 °C (lit.)
SMILES字符串
O=C(C1CC1)c2ccccc2
InChI
1S/C10H10O/c11-10(9-6-7-9)8-4-2-1-3-5-8/h1-5,9H,6-7H2
InChI key
PJRHFTYXYCVOSJ-UHFFFAOYSA-N
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应用
Cyclopropyl phenyl ketone was used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It was used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
Cyclopropyl substituent effects on acid-catalyzed hydration of alkenes. Correlation by σ+ parameters.
Journal of the American Chemical Society, 98(4), 947-951 (1976)
Enolate formation from cyclopropyl ketones via iodide-induced ring opening and its use for stereoselective aldol reaction.
Tetrahedron, 57(6), 987-995 (2001)
Physical chemistry chemical physics : PCCP, 22(5), 2870-2877 (2020-01-09)
The two hydrogen bond solvation sites exhibited by the carbonyl group in acetophenone are influenced by alkylation of the methyl group in both the acetophenone and in the prototype solvent methanol, largely due to London dispersion forces. Phenyl docking and
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