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![9-氧杂二环[6.1.0]壬-4-烯 95%](/deepweb/assets/sigmaaldrich/product/structures/328/338/c44d0a8d-81ab-4a17-81bb-aebb26a006e7/640/c44d0a8d-81ab-4a17-81bb-aebb26a006e7.png)
质量水平
检测方案
95%
形式
liquid
包含
100-200 ppm Irganox 1076 FD as antioxidant
折射率
n20/D 1.469 (lit.)
bp
145-146 °C (lit.)
mp
−16 °C (lit.)
溶解性
H2O: insoluble
密度
0.846 g/mL at 25 °C (lit.)
SMILES字符串
C1CCCC=CCC1
InChI
1S/C8H14/c1-2-4-6-8-7-5-3-1/h1-2H,3-8H2/b2-1-
InChI key
URYYVOIYTNXXBN-UPHRSURJSA-N
一般描述
二氯三（三苯基膦）钌（II）催化顺式-环辛烯与四氯化碳进行加成反应，得到 1-氯-4-（三氯甲基）环辛烷（1，4-加合物）。它通过掺入介孔二氧化硅涂层的磁铁矿纳米粒子的介孔二氧化硅壳中的氧化钼纳米粒子催化进行环氧化。
应用
顺式-环辛烯已被用于通过扫描隧道显微镜研究化学吸附在在硅（100）上的烯烃。
其他说明
含有环辛烷
Radical reactions in the coordination sphere. 4. Addition of carbon tetrachloride to cis-cyclooctene catalyzed by dichlorotris (triphenylphosphine) ruthenium (II).
Matsumoto H, et al.
The Journal of Organic Chemistry, 43(9), 1734-1736 (1978)
A magnetically recyclable nanocomposite catalyst for olefin epoxidation.
Mohammadreza Shokouhimehr et al.
Angewandte Chemie (International ed. in English), 46(37), 7039-7043 (2007-08-10)
Voltage-dependent STM images of covalently bound molecules on Si (100).
Padowitz DF and Hamers RJ.
The Journal of Physical Chemistry B, 102(43), 8541-8545 (1998)
Xiao-Song Xue et al.
Chemical reviews, 117(13), 8622-8648 (2017-03-11)
The most fundamental concepts in chemistry are structure, energetics, reactivity and their inter-relationships, which are indispensable for promoting chemistry into a rational science. In this regard, bond energy, the intrinsic determinant directly related to structure and reactivity, should be most
Anyang Peng et al.
Science advances, 6(5), eaax6637-eaax6637 (2020-02-18)
Traditionally, a catalyst functions by direct interaction with reactants. In a new noncontact catalytic system (NCCS), an intermediate produced by one catalytic reaction serves as an intermediary to enable an independent reaction to proceed. An example is the selective oxidation
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