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质量水平
检测方案
97%
形式
liquid
包含
~0.1% hydroquinone as stabilizer
杂质
3% benzene
折射率
n20/D 1.472 (lit.)
bp
88-89 °C (lit.)
密度
0.847 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C1C=CCC=C1
InChI
1S/C6H8/c1-2-4-6-5-3-1/h1-2,5-6H,3-4H2
InChI key
UVJHQYIOXKWHFD-UHFFFAOYSA-N
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一般描述
1,4-环己二烯是催化加氢反应的有效氢供体。它能迅速地用氢取代N-苄氧基氨基甲酸酯、苄酯、苄醚和苄胺的苄基。在钌 (II)-三苯基膦催化剂存在下在高温下形成苯。
应用
以1,4-环己二烯 (1,4-CHD) 为研究对象,研究了1,4-CHD 在强激光脉冲照射下的重碎裂形成母离子的过程。
用于电子转移介导的开环反应中形成的自由基中间体的还原
警示用语:
Danger
危险分类
Carc. 1A - Flam. Liq. 2 - Muta. 1B - STOT RE 2
靶器官
Blood
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
法规信息
危险化学品
Rapid removal of protecting groups from peptides by catalytic transfer hydrogenation with 1, 4-cyclohexadiene.
The Journal of Organic Chemistry, 43(21), 4194-4196 (1978)
A key factor in parent and fragment ion formation on irradiation with an intense femtosecond laser pulse.
Chemical Physics Letters, 342(5), 563-570 (2001)
Dalton transactions (Cambridge, England : 2003), 41(11), 3185-3193 (2012-01-31)
Relatively little is known about structural transformations of very small metal clusters that result from the adsorption of molecules. Here, the ligand-induced structural transformation of Ag(5)(+)(g) by 1,4-cyclohexadiene, which is capable of binding metal clusters as a bidentate ligand, is
Physical review letters, 108(25), 253006-253006 (2012-09-26)
We report the first study of UV-induced photoisomerization probed via core ionization by an x-ray laser. We investigated x-ray ionization and fragmentation of the cyclohexadiene-hexatriene system at 850 eV during the ring opening. We find that the ion-fragmentation patterns evolve
Chemical communications (Cambridge, England), 47(1), 215-217 (2010-08-24)
A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.
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