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Merck
CN

125237

Sigma-Aldrich

4-氯硫代苯酚

97%

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别名:
4-氯苯硫酚, 对氯苯硫醇
线性分子式:
ClC6H4SH
CAS号:
分子量:
144.62
Beilstein:
605971
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

97%

形式

solid

bp

205-207 °C (lit.)

mp

49-51 °C (lit.)

溶解性

methanol: soluble

SMILES字符串

Sc1ccc(Cl)cc1

InChI

1S/C6H5ClS/c7-5-1-3-6(8)4-2-5/h1-4,8H

InChI key

VZXOZSQDJJNBRC-UHFFFAOYSA-N

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一般描述

4-氯硫酚在四苯基铁 (III)-腐生素的催化下发生氧化偶联反应,生成二硫化物

应用

反应物参与到:
  • 钴盐催化剂和空气氧化剂氧化合成二硫化物
  • 硫脲催化 sulfa-Michael 加成反应
  • 普默尔型环化
  • C-H 活化和 C-S 与杂环的交叉偶联
  • 烯丙基亚磺酰化与烯丙基碳酸酯
  • Lewis 酸催化的 2-芳基-3,4-二氢吡喃的亲电开环反应
用对氯硫酚改性聚氯乙烯,合成了含卤素基团的聚氯乙烯

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危险声明

危险分类

Acute Tox. 4 Oral - Skin Corr. 1B

WGK

WGK 3

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Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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