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经验公式(希尔记法):
C10H14O
化学文摘社编号:
分子量:
150.22
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
229-352-5
Beilstein/REAXYS Number:
2206714
MDL number:
产品名称
(R)-(-)-香芹酮, 98%
InChI key
ULDHMXUKGWMISQ-SECBINFHSA-N
InChI
1S/C10H14O/c1-7(2)9-5-4-8(3)10(11)6-9/h4,9H,1,5-6H2,2-3H3/t9-/m1/s1
SMILES string
CC(=C)[C@@H]1CC=C(C)C(=O)C1
vapor density
5.2 (vs air)
vapor pressure
0.4 mmHg ( 20 °C)
assay
98%
form
liquid
optical activity
[α]20/D −61°, neat
refractive index
n20/D 1.497 (lit.)
bp
227-230 °C (lit.)
density
0.959 g/mL at 25 °C (lit.)
functional group
ketone
Quality Level
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Application
(R)-(−)-香芹酮可用作合成对映纯(R)-(+)-3-甲基-6-异丙烯基-环庚-3-烯酮-1(一种在萜类化合物合成过程中形成的有用中间体)的起始试剂。它可以用作合成不同保护的(4S,6R,7R)-三羟基-1-辛炔衍生物的起始试剂。
手性原料。
General description
(R)-(−)-香芹酮是一种单萜类化合物。其在气相中的臭氧分解反应已有报道。醛(甲醛)和双自由基为主要产物。它可参与非手性八唑酮的非对映选择性合成。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Skin Sens. 1
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
192.2 °F - closed cup
flash_point_c
89 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Yoshiyuki Yamada et al.
Neuron, 93(5), 1198-1212 (2017-02-28)
Sensory information is translated into ensemble representations by various populations of projection neurons in brain circuits. The dynamics of ensemble representations formed by distinct channels of output neurons in diverse behavioral contexts remains largely unknown. We studied the two output
Gas-phase ozonolysis of the monoterpenoids (S)-(+)-carvone,(R)-(-)-carvone,(-)-carveol, geraniol and citral.
Nunes FMN, et al.
Atmospheric Environment, 39(40), 7715-7730 (2005)
Bryostatin: A novel asymmetric synthesis of the C27-C34 fragment starting from (R)-carvone as chiral template.
De Brabander J, et al.
Tetrahedron Asymmetry, 8(11), 1721-1724 (1997)
An improved synthesis of homochiral octalones from (-)-carvone.
Tenius BSM, et al.
Tetrahedron Asymmetry, 4(4), 633-636 (1993)
Liebigs Ann. Chem., 403-403 (1993)
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