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Merck
CN

124303

Sigma-Aldrich

叔丁基苯基碳酸酯

98%

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别名:
1,1-Dimethylethyl phenyl carbonate, 1-tert-Butoxycarbonyloxybenzene, Phenyl tert-butyl carbonate
线性分子式:
(CH3)3COCOOC6H5
CAS号:
分子量:
194.23
Beilstein:
2361602
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

形式

liquid

bp

83 °C/0.6 mmHg (lit.)

密度

1.05 g/mL at 20 °C (lit.)

SMILES字符串

CC(C)(C)OC(=O)Oc1ccccc1

InChI

1S/C11H14O3/c1-11(2,3)14-10(12)13-9-7-5-4-6-8-9/h4-8H,1-3H3

InChI key

UXWVQHXKKOGTSY-UHFFFAOYSA-N

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应用

tert-Butyl phenyl carbonate was used in determination of octanol-water partition coefficients by microemulsion electrokinetic chromatography. It was also used in the synthesis of 2-nitroindoles. It was used as reagent for mono-Boc protection of α,ω-diamines.

WGK

WGK 3

闪点(°F)

closed cup

闪点(°C)

closed cup

个人防护装备

Eyeshields, Gloves

法规信息

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Synthesis of 2-nitroindoles via the Sundberg indole synthesis.
Pelkey ET and Gribble GW.
Tetrahedron Letters, 38(32), 5603-5606 (1997)
Jesper Østergaard et al.
Electrophoresis, 24(6), 1038-1046 (2003-03-27)
Microemulsion electrokinetic chromatography (MEEKC) was assessed as a tool for determination of octanol-water partition coefficients using 34 solutes encompassing 8 carbonate esters. It was confirmed that microemulsions containing 1.44-2.88% w/w SDS, 6.49% w/w 1-butanol, and 0.82% w/w n-heptane constitute a
Organic Syntheses, 84, 209-209 (2007)

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