质量水平
检测方案
96%
形式
liquid
折射率
n20/D 1.4409 (lit.)
bp
120-121 °C (lit.)
mp
−112 °C (lit.)
溶解性
H2O: slightly soluble at 16.5 °C (0.02g/100ml)
alcohol: miscible
diethyl ether: miscible
密度
1.261 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(C)CCBr
InChI
1S/C5H11Br/c1-5(2)3-4-6/h5H,3-4H2,1-2H3
InChI key
YXZFFTJAHVMMLF-UHFFFAOYSA-N
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一般描述
1-溴-3-甲基丁烷是一种低毒性的溴溶剂。
应用
1-溴-3-甲基丁烷用于合成1-(3-甲基丁基)吡咯。它可通过直接的光解制备法用于戊基过氧自由基的生成。它还可作为萃取溶剂，通过液-液微萃取结合气相色谱-质谱法对水样中的多环芳烃进行测定。
警示用语：
Danger
危险分类
Aquatic Chronic 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Mei-I Leong et al.
Journal of chromatography. A, 1217(34), 5455-5461 (2010-07-29)
A low toxic dispersive liquid-liquid microextraction (LT-DLLME) combined with gas chromatography-mass spectrometry (GC-MS) had been developed for the extraction and determination of 16 polycyclic aromatic hydrocarbons (PAHs) in water samples. In normal DLLME assay, chlorosolvent had been widely used as
Erin N Sharp et al.
The journal of physical chemistry. A, 112(7), 1445-1456 (2008-01-24)
Cavity ringdown spectra of the A-X electronic transition of all eight isomers of the pentyl peroxy radical are reported. Using the corresponding assignments from previously studied smaller alkyl peroxy radicals, assignments of origin bands are made for the pentyl peroxy
J Stephen Elmore et al.
Journal of agricultural and food chemistry, 56(15), 6173-6179 (2008-07-16)
Wheat flour from plants deficient in sulfur has been shown to contain substantially higher levels of free amino acids, particularly asparagine and glutamine, than flour from wheat grown where sulfur nutrition was sufficient. Elevated levels of asparagine resulted in acrylamide
Guilong Peng et al.
Archives of environmental contamination and toxicology, 70(3), 607-614 (2015-11-29)
A low toxic solvent-based vortex-assisted surfactant-enhanced emulsification liquid-liquid microextraction (LT-VSLLME) combined with graphite furnace atomic absorption spectrometry was developed for the extraction and determination of lead (Pb) in water samples. In the LT-VSLLME method, the extraction solvent was dispersed into
Xiaojie Zhao et al.
Journal of chromatography. A, 1587, 197-208 (2018-12-26)
Ionic liquid bonded polysiloxanes (PILs) are a class of polysiloxanes whose side chains contain ionic liquid (IL) moieties. Considering their excellent selectivity and thermo-stability, PILs have great potentials in the development of polar stationary phases for gas chromatography. In this
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