124087
2-溴-4-甲基苯胺
98%
别名:
2-溴-对甲苯胺, 4-氨基-3-溴甲苯
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关于此项目
线性分子式:
BrC6H3(CH3)NH2
化学文摘社编号:
分子量:
186.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-515-7
Beilstein/REAXYS Number:
1931711
MDL number:
产品名称
2-溴-4-甲基苯胺, 98%
InChI key
UVRRJILIXQAAFK-UHFFFAOYSA-N
InChI
1S/C7H8BrN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3
SMILES string
Cc1ccc(N)c(Br)c1
assay
98%
form
liquid
refractive index
n20/D 1.602 (lit.)
bp
240 °C (lit.)
mp
14-16 °C (lit.)
density
1.5 g/mL at 25 °C (lit.)
functional group
bromo
Quality Level
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Application
2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.
General description
2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me3Al to form amide.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Synthesis and reactivity of ortho-palladated arylcarbodiimides and aryl isothiocyanates. Formation of C-palladated quinazolines. Synthesis of 2-aminoquinolines.
Vicente J, et al.
Organometallics, 23(20), 4711-4722 (2004)
Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation.
Koubachi J, et al.
Tetrahedron, 66(10), 1937-1946 (2010)
Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation.
Hostyn S, et al.
Tetrahedron, 62(19), 4676-4684 (2006)
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