推荐产品
质量水平
检测方案
98%
形式
liquid
折射率
n20/D 1.602 (lit.)
bp
240 °C (lit.)
mp
14-16 °C (lit.)
密度
1.5 g/mL at 25 °C (lit.)
SMILES字符串
Cc1ccc(N)c(Br)c1
InChI
1S/C7H8BrN/c1-5-2-3-7(9)6(8)4-5/h2-4H,9H2,1H3
InChI key
UVRRJILIXQAAFK-UHFFFAOYSA-N
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一般描述
2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me3Al to form amide.
应用
2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.
警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Synthesis and reactivity of ortho-palladated arylcarbodiimides and aryl isothiocyanates. Formation of C-palladated quinazolines. Synthesis of 2-aminoquinolines.
Vicente J, et al.
Organometallics, 23(20), 4711-4722 (2004)
Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation.
Koubachi J, et al.
Tetrahedron, 66(10), 1937-1946 (2010)
Synthesis of 7H-indolo [2, 3-c] quinolines: study of the Pd-catalyzed intramolecular arylation of 3-(2-bromophenylamino) quinolines under microwave irradiation.
Hostyn S, et al.
Tetrahedron, 62(19), 4676-4684 (2006)
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