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质量水平
检测方案
99%
形式
liquid
折射率
n20/D 1.576 (lit.)
bp
196 °C (lit.)
密度
1.63 g/mL at 25 °C (lit.)
SMILES字符串
Clc1cccc(Br)c1
InChI
1S/C6H4BrCl/c7-5-2-1-3-6(8)4-5/h1-4H
InChI key
JRGGUPZKKTVKOV-UHFFFAOYSA-N
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一般描述
1-溴-3-氯苯与 i -PrMgCl-LiCl 在 THF 中 0°C 下发生溴-镁交换反应，并被吸电子取代基强烈加速 。它被作为测试底物，用于研究以 K 4 [Fe (CN) 6 ] 为氰基源，在各种卤代芳烃氰化反应中使用新型催化系统的应用 。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2
WGK
WGK 3
闪点(°F)
176.0 °F
闪点(°C)
80 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Silvina C Pérez et al.
Solid state nuclear magnetic resonance, 87, 18-23 (2017-07-01)
A simple model to explain the NQR lineshape in solids with orientational disorder or substitutional disorder is presented. The particular case of m-chlorobromobenzene is studied. It is based on the assumption that Bromine atoms, of m-chlorobromobenzene molecules, behave as point
K Schümann et al.
European journal of clinical investigation, 34(4), 275-282 (2004-04-17)
Iron regulatory protein 1 (IRP1), a post-transcriptional regulator of iron metabolism, is activated in the duodenum of iron-deficient animals, which is associated with increased iron absorption. In cell cultures IRP1 was also activated by iron-independent signals, such as H(2)O(2). Here
An efficient palladium catalytic system for microwave assisted cyanation of aryl halides.
Hajipour AR, et al.
Journal of Organometallic Chemistry, 696(4), 819-824 (2011)
Lei Shi et al.
The Journal of organic chemistry, 74(7), 2760-2764 (2009-03-14)
Competition experiments have been performed to determine the relative reactivities of substituted bromobenzenes, bromonaphthalenes, and 9-bromoanthracene toward i-PrMgCl x LiCl in THF at 0 degrees C. The rates of the bromine-magnesium exchange reactions are accelerated by electron-acceptor substituents, the activating
Nicholas C Pflug et al.
Environmental science & technology, 53(9), 4813-4822 (2019-03-27)
Anilines have been shown to be especially susceptible to single-electron oxidation by excited triplet-state photosensitizers (3sens*), and thus, are good potential candidates to probe the oxidative properties of triplet-state chromophoric dissolved organic matter (3CDOM*). However, steady-state experiments tend to underestimate
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